Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 2 5 2002 10.5194/acpd-2-1287-2002 http://www.atmos-chem-phys-discuss.net/2/1287/2002/ http://www.atmos-chem-phys-discuss.net/2/1287/2002/acpd-2-1287-2002.html http://www.atmos-chem-phys-discuss.net/2/1287/2002/acpd-2-1287-2002.pdf 1287 1315 2002-09-05 Aerosol sources and their contribution to the chemical composition of aerosols in the Eastern Mediterranean Sea during summertime J. Sciare H. Bardouki C. Moulin N. Mihalopoulos LSCE, Orme des Merisiers, Bat 709, CE Saclay, 91191 Gif-sur-Yvette Cedex, France Environmental Chemical Processes Laboratory, Department of Chemistry, University of Crete, P.O. Box 1470, 71409 Heraklion, Greece A detailed study on the temporal variability of compounds important in controlling aerosol chemical composition was performed during a one-month experiment conducted during summer 2000 at a background site on Crete, in the Eastern Mediterranean Sea. Contribution of different aerosol sources in the Eastern Mediterranean Basin could be investigated at this location since the site is influenced by a wide range of air masses originating mainly in Europe and Africa. Chemical apportionment was performed for various air mass origins and showed a strong impact of anthropogenic emissions in the Turkey and Central Europe sectors, with black carbon (BC) and non-sea-salt sulfate (nss-SO₄) concentrations being almost a factor of two higher than observed in the Eastern and Western Europe sectors. High levels of non-sea-salt calcium (nss-Ca) were associated with air masses from Africa but also from Central Turkey. Evidence was found that BC calculation based on light absorbance during dust events was biased. A source-oriented model was applied for these compounds as well as for sulfur dioxide (SO₂), in order to examine the source-receptor relationships responsible for the observed levels in Crete. Among the results obtained from this model, the major contribution of Turkey and Central Europe was confirmed in terms of anthropogenic emissions. Comparisons with remote optical properties obtained from Satellite observations (SEAWIFS) north of Crete indicates that our ground based aerosol characterization was suitable for describing aerosol properties in the atmospheric column for most of the time during the campaign.