<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-2-1261-2002</article-id>
<title-group>
<article-title>A discussion on the determination of atmospheric OH and its trends</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Jöckel</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Brenninkmeijer</surname>
<given-names>C. A. M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Crutzen</surname>
<given-names>P. J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Max Planck Institute for Chemistry POB 3060, 55020 Mainz, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>30</day>
<month>08</month>
<year>2002</year>
</pub-date>
<volume>2</volume>
<issue>4</issue>
<fpage>1261</fpage>
<lpage>1286</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/2/1261/2002/acpd-2-1261-2002.html">This article is available from http://www.atmos-chem-phys-discuss.net/2/1261/2002/acpd-2-1261-2002.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/2/1261/2002/acpd-2-1261-2002.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/2/1261/2002/acpd-2-1261-2002.pdf</self-uri>
<abstract>
<p>The global hydroxyl radical distribution largely determines the oxidation
      efficiency of the atmosphere and, together with their sources and atmospheric
      transport, the distributions and lifetimes of most trace gases. Because of
      the great importance of several of these gases for climate, ozone budget and
      OH itself, it is of fundamental importance to acquire knowledge about atmospheric
      OH and possible trends in its concentrations. In the past, average concentrations of
      OH and trends were largely derived using industrially produced CH&lt;sub&gt;3&lt;/sub&gt;CCl&lt;sub&gt;3&lt;/sub&gt; as a chemical tracer. The analyses
      have given valuable, but also rather uncertain results. In this paper we describe an idealized computer aided tracer experiment which has as one of
      its goals to derive tracer concentration weighted, global average &amp;lt;k(OH)&amp;gt;, where
      he temporal and spatial OH distribution is prescribed and k is the reaction rate coefficient of OH with a hitherto never produced (Gedanken)
      tracer, which is injected at a number of surface sites in the atmosphere in
      well known amounts over a given time period. Using a three-dimensional (3D)
      time-dependent chemistry/transport model &amp;lt;k(OH)&amp;gt;
      can be accurately determined from the calculated 3-D tracer distribution. It is next explored how well
      &amp;lt;k(OH)&amp;gt;
      can be retrieved solely from tracer measurements at a limited number of surface sites. The results from this analysis are encouraging enough to
      actually think about the feasibility to carry out a global dedicated tracer
      experiment to derive &amp;lt;k(OH)&amp;gt;
      and its temporal trends. However, before that, we propose to test the methods which are used to derive
      &amp;lt;k(OH)&amp;gt;, so far largely
      using CH&lt;sub&gt;3&lt;/sub&gt;CCl&lt;sub&gt;3&lt;/sub&gt;, with an idealized tracer experiment, in which a
      global model is used to calculate the &amp;quot;Gedanken&quot;&amp;nbsp; tracer distribution,
      representing the real 3-D world, from which we next derive &amp;lt;k(OH)&amp;gt;, using only
      the tracer information from a limited set of surface sites. We propose here
      that research groups which are, or will be, involved in global average OH studies to participate in such an inter-comparison of methods, organized and
      over-seen by a committee appointed by the International Global Atmospheric
      Chemistry (IGAC) program.</p>
</abstract>
<counts><page-count count="26"/></counts>
</article-meta>
</front>
<body/>
<back>
</back>
</article>