Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 2 1 2002 10.5194/acpd-2-1-2002 http://www.atmos-chem-phys-discuss.net/2/1/2002/ http://www.atmos-chem-phys-discuss.net/2/1/2002/acpd-2-1-2002.html http://www.atmos-chem-phys-discuss.net/2/1/2002/acpd-2-1-2002.pdf 1 28 2002-01-11 Accommodation coefficient of HOBr on deliquescent sodium bromide aerosol particles M. Wachsmuth H. W. Gäggeler R. von Glasow M. Ammann Paul Scherrer Institut, Laboratory for Radio- and Environmental Chemistry, Villigen, Switzerland Also at Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland Max-Planck-Institut für Chemie, Abt. Chemie der Atmosphäre, Mainz, Germany Present address: Center for Atmospheric Sciences, Scripps Institution of Oceanography, University of California, San Diego, USA Uptake of HOBr on sea salt aerosol, sea salt brine or ice is believed to be a key process providing a source of photolabile bromine (Br₂) and sustaining ozone depletion cycles in the arctic troposphere. In the present study, uptake of HOBr on sodium bromide (NaBr) aerosol particles was investigated at an extremely low HOBr concentration of 300 cm^-3 using the short-lived radioactive isotopes ^83-86Br. Under these conditions, at maximum one HOBr molecule was taken up per particle. The rate of uptake was clearly limited by the mass accommodation coefficient, which was calculated to be 0.6±0.2. This value is a factor of 10 larger than estimates used in earlier models. The atmospheric implications are discussed using the box model "MOCCA'', showing that the increase of the accommodation coefficient of HOBr by a factor of 10 only slightly affects net ozone loss, but significantly increases chlorine release.