Atmos. Chem. Phys. Discuss., 14, 2307-2362, 2014
www.atmos-chem-phys-discuss.net/14/2307/2014/
doi:10.5194/acpd-14-2307-2014
© Author(s) 2014. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
TransCom N2O model inter-comparison – Part 1: Assessing the influence of transport and surface fluxes on tropospheric N2O variability
R. L. Thompson1,2, P. K. Patra3, K. Ishijima3, E. Saikawa4,5, M. Corazza6, U. Karstens7, C. Wilson8, P. Bergamaschi6, E. Dlugokencky9, C. Sweeney9, R. G. Prinn4, R. F. Weiss10, S. O'Doherty11, P. J. Fraser12, L. P. Steele12, P. B. Krummel12, M. Saunois2, M. Chipperfield8, and P. Bousquet2
1Norwegian Institute for Air Research, Kjeller, Norway
2Laboratoire des Sciences du Climat et l'Environnement, Gif sur Yvette, France
3Research Institute for Global Change, JAMSTEC, Yokohama, Japan
4Center for Global Change Science, MIT, Cambridge, MA, USA
5Department of Environmental Studies, Emory University, GA, USA
6Institute for Environment and Sustainability, Joint Research Centre, European Commission, Ispra, Italy
7Max Planck Institute for Biogeochemistry, Jena, Germany
8School of Earth and Environment, University of Leeds, Leeds, UK
9NOAA Earth System Research Laboratory, Global Monitoring Division, Boulder, CO, USA
10Scripps Institution of Oceanography, La Jolla, CA, USA
11School of Chemistry, University of Bristol, Bristol, UK
12Centre for Australian Weather and Climate Research, CSIRO, Marine and Atmospheric Research, Aspendale, Victoria, Australia

Abstract. We present a comparison of chemistry-transport models (TransCom-N2O) to examine the importance of atmospheric transport and surface fluxes on the variability of N2O mixing ratios in the troposphere. Six different models and two model variants participated in the inter-comparison and simulations were made for the period 2006 to 2009. In addition to N2O, simulations of CFC-12 and SF6 were made by a subset of four of the models to provide information on the models proficiency in stratosphere-troposphere exchange (STE) and meridional transport, respectively. The same prior emissions were used by all models to restrict differences among models to transport and chemistry alone. Four different N2O flux scenarios totalling between 14 and 17 Tg N yr−1 (for 2005) globally were also compared. The modelled N2O mixing ratios were assessed against observations from in-situ stations, discrete air sampling networks, and aircraft. All models adequately captured the large-scale patterns of N2O and the vertical gradient from the troposphere to the stratosphere and most models also adequately captured the N2O tropospheric growth rate. However, all models underestimated the inter-hemispheric N2O gradient by at least 0.33 ppb (equivalent to 1.5 Tg N), which, even after accounting for an overestimate of emissions in the Southern Ocean of circa 1.0 Tg N, points to a likely underestimate of the Northern Hemisphere source by up to 0.5 Tg N and/or an overestimate of STE in the Northern Hemisphere. Comparison with aircraft data reveal that the models overestimate the amplitude of the N2O seasonal cycle at Hawaii (21° N, 158° W) below circa 6000 m, suggesting an overestimate of the importance of stratosphere to troposphere transport in the lower troposphere at this latitude. In the Northern Hemisphere, most of the models that provided CFC-12 simulations captured the phase of the CFC-12, seasonal cycle, indicating a reasonable representation of the timing of STE. However, for N2O all models simulated a too early minimum by 2 to 3 months owing to errors in the seasonal cycle in the prior soil emissions, which is still not adequately represented by terrestrial biosphere models. In the Southern Hemisphere, most models failed to capture the N2O and CFC-12 seasonality at Cape Grim, Tasmania, and all failed at the South Pole, whereas for SF6, all models could capture the seasonality at all sites, suggesting that there are large errors in modeled vertical transport in high southern latitudes.

Citation: Thompson, R. L., Patra, P. K., Ishijima, K., Saikawa, E., Corazza, M., Karstens, U., Wilson, C., Bergamaschi, P., Dlugokencky, E., Sweeney, C., Prinn, R. G., Weiss, R. F., O'Doherty, S., Fraser, P. J., Steele, L. P., Krummel, P. B., Saunois, M., Chipperfield, M., and Bousquet, P.: TransCom N2O model inter-comparison – Part 1: Assessing the influence of transport and surface fluxes on tropospheric N2O variability, Atmos. Chem. Phys. Discuss., 14, 2307-2362, doi:10.5194/acpd-14-2307-2014, 2014.
 
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