Atmos. Chem. Phys. Discuss., 13, 9733-9750, 2013
www.atmos-chem-phys-discuss.net/13/9733/2013/
doi:10.5194/acpd-13-9733-2013
© Author(s) 2013. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Influence of aerosol lifetime on the interpretation of nucleation experiments with respect to the first nucleation theorem
S. Ehrhart and J. Curtius
Institute for Atmospheric and Environmental Sciences, Goethe University of Frankfurt am Main, Germany

Abstract. The SAWNUC microphysical aerosol nucleation model is used to study the effect of reactor walls on the interpretation of nucleation experiments with respect to nucleation theory. This work shows that loss processes, such as wall losses, influence the interpretation of nucleation experiments, especially at low growth rates and short lifetime of freshly nucleated particles. In these cases the power dependency of the formation rates, determined at a certain particle size, with respect to H2SO4 does not correspond to the approximate number of H2SO4 molecules in the critical cluster as expected by the first nucleation theorem. Observed ∂log(J)/∂log([H2SO4]) therefore can vary widely for identical nucleation conditions but different sink terms.

Citation: Ehrhart, S. and Curtius, J.: Influence of aerosol lifetime on the interpretation of nucleation experiments with respect to the first nucleation theorem, Atmos. Chem. Phys. Discuss., 13, 9733-9750, doi:10.5194/acpd-13-9733-2013, 2013.
 
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