Atmos. Chem. Phys. Discuss., 13, 2955-2995, 2013
www.atmos-chem-phys-discuss.net/13/2955/2013/
doi:10.5194/acpd-13-2955-2013
© Author(s) 2013. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Satellite observation of lowermost tropospheric ozone by multispectral synergism of IASI thermal infrared and GOME-2 ultraviolet measurements
J. Cuesta1, M. Eremenko1, X. Liu2, G. Dufour1, Z. Cai3, M. Höpfner4, T. von Clarmann4, P. Sellitto1, G. Foret1, B. Gaubert1, M. Beekmann1, J. Orphal4, K. Chance2, R. Spurr5, and J.-M. Flaud1
1Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR7583, CNRS, Université Paris Est Créteil, Université Paris Diderot, Créteil, France
2Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts, USA
3Key Laboratory of Middle Atmosphere and Global Environment Observation, Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences, Beijing, China
4Karlsruher Institut für Technologie (KIT), Institut für Meteorologie und Klimaforschung, Karlsruhe, Germany
5RT Solutions Inc., Cambridge, USA

Abstract. We present a new multispectral approach for observing lowermost tropospheric ozone from space by synergism of atmospheric radiances in the thermal infrared (TIR) observed by IASI and earth reflectances in the ultraviolet (UV) measured by GOME-2. Both instruments are onboard the series of MetOp satellites (in orbit since 2006 and expected until 2022) and their scanning capabilities offer global coverage every day, with a relatively fine ground pixel resolution (12-km-diameter pixels spaced by 25 km for IASI at nadir). Our technique uses altitude-dependent Tikhonov-Phillips-type constraints, which optimize sensitivity to lower tropospheric ozone. It integrates the VLIDORT and KOPRA radiative transfer codes for simulating UV reflectance and TIR radiance, respectively. We have used our method to analyse real observations over Europe during an ozone pollution episode in the summer of 2009. The results show that the multispectral synergism of IASI (TIR) and GOME-2 (UV) enables the observation of the spatial distribution of ozone plumes in the lowermost troposphere (LMT, from the surface up to 3 km a.s.l., above sea level), in good quantitative agreement with the CHIMERE regional chemistry-transport model. When high ozone concentrations extend vertically above 3 km a.s.l., they are similarly observed over land by both the multispectral and IASI retrievals. On the other hand, ozone plumes located below 3 km a.s.l. are only clearly depicted by the multispectral retrieval (both over land and over ocean). This is achieved by a clear enhancement of sensitivity to ozone in the lowest atmospheric layers. The multispectral sensitivity in the LMT peaks at 2 to 2.5 km a.s.l. over land, while sensitivity for IASI or GOME-2 only peaks at 3 to 4 km a.s.l. at lowest (above the LMT). The degrees of freedom for the multispectral retrieval increase by 40% (21%) with respect to IASI only retrievals for atmospheric partial columns up to 3 km a.s.l. (6 km a.s.l.). Validations with ozonesondes show that our synergetic approach for combining IASI (TIR) and GOME-2 (UV) measurements retrieves lowermost tropospheric ozone with a mean bias of 2% and a precision of 16%, when smoothing by the retrieval vertical sensitivity (1% mean bias and 24% precision for direct comparisons).

Citation: Cuesta, J., Eremenko, M., Liu, X., Dufour, G., Cai, Z., Höpfner, M., von Clarmann, T., Sellitto, P., Foret, G., Gaubert, B., Beekmann, M., Orphal, J., Chance, K., Spurr, R., and Flaud, J.-M.: Satellite observation of lowermost tropospheric ozone by multispectral synergism of IASI thermal infrared and GOME-2 ultraviolet measurements, Atmos. Chem. Phys. Discuss., 13, 2955-2995, doi:10.5194/acpd-13-2955-2013, 2013.
 
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