Atmos. Chem. Phys. Discuss., 13, 24925-24973, 2013
www.atmos-chem-phys-discuss.net/13/24925/2013/
doi:10.5194/acpd-13-24925-2013
© Author(s) 2013. This work is distributed
under the Creative Commons Attribution 3.0 License.
Review Status
This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Impacts of different plant functional types on ambient ozone predictions in the Seoul Metropolitan Areas (SMA), Korea
H.-K. Kim1, J.-H. Woo1, R. S. Park2, C. H. Song2, J.-H. Kim3, S.-J. Ban4, and J.-H. Park4
1Department of Advanced Technology Fusion, Konkuk University, Seoul, Korea
2School of Environmental Science and Engineering, Gwangju Institute of Science and Technology, Gwangju, Korea
3Green-ECOS, Seoul, Korea
4Air Quality Research Division, National Institute of Environmental Research, Incheon, Korea

Abstract. Plant functional type (PFT) distributions affect the results of biogenic emission modeling as well as O3 and PM simulations using chemistry-transport models (CTMs). This paper analyzes the variations of both surface biogenic VOC emissions and O3 concentrations due to changes in the PFT distributions in the Seoul Metropolitan Areas, Korea. Also, this paper attempts to provide important implications for biogenic emissions modeling studies for CTM simulations. MM5-MEGAN-SMOKE-CMAQ model simulations were implemented over the Seoul Metropolitan Areas in Korea to predict surface O3 concentrations for the period of 1 May to 31 June 2008. Starting from MEGAN biogenic emissions analysis with three different sources of PFT input data, US EPA CMAQ O3 simulation results were evaluated by surface O3 monitoring datasets and further considered on the basis of geospatial and statistical analyses. The three PFT datasets considered were "(1)KORPFT", developed with a region specific vegetation database; (2) CDP, adopted from US NCAR; and (3) MODIS, reclassified from the NASA Terra and Aqua combined land cover products. Comparisons of MEGAN biogenic emission results with the three different PFT data showed that broadleaf trees (BT) are the most significant contributor, followed by needleleaf trees (NT), shrub (SB), and herbaceous plants (HB) to the total biogenic volatile organic compounds (BVOCs). In addition, isoprene from BT and terpene from NT were recognized as significant primary and secondary BVOC species in terms of BVOC emissions distributions and O3-forming potentials in the study domain. Multiple regression analyses with the different PFT data (δO3 vs. δPFTs) suggest that KORPFT can provide reasonable information to the framework of MEGAN biogenic emissions modeling and CTM O3 predictions. Analyses of the CMAQ performance statistics suggest that deviations of BT areas can significantly affect CMAQ isoprene and O3 predictions. From further evaluations of the isoprene and O3 prediction results, we explored the PFT area-loss artifact that occurs due to geographical disparity between the PFT and leaf area index distributions, and can cause increased bias in CMAQ O3. Thus, the PFT-loss artifact must be a source of limitation in the MEGAN biogenic emission modeling and the CTM O3 simulation results. Time changes of CMAQ O3 distributions with the different PFT scenarios suggest that hourly and local impacts from the different PFT distributions on occasional inter-deviations of O3 are quite noticeable, reaching up to 10 ppb. Exponentially diverging hourly BVOC emissions and O3 concentrations with increasing ambient temperature suggest that the use of representative PFT distributions becomes more critical for O3 air quality modeling (or forecasting) in support of air quality decision-making and human health studies.

Citation: Kim, H.-K., Woo, J.-H., Park, R. S., Song, C. H., Kim, J.-H., Ban, S.-J., and Park, J.-H.: Impacts of different plant functional types on ambient ozone predictions in the Seoul Metropolitan Areas (SMA), Korea, Atmos. Chem. Phys. Discuss., 13, 24925-24973, doi:10.5194/acpd-13-24925-2013, 2013.
 
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