Atmos. Chem. Phys. Discuss., 13, 20195-20238, 2013
www.atmos-chem-phys-discuss.net/13/20195/2013/
doi:10.5194/acpd-13-20195-2013
© Author(s) 2013. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
In-situ physical and chemical characterization of the Eyjafjallajökull aerosol plume in the free troposphere over Italy
S. Sandrini1, L. Giulianelli1, S. Decesari1, M. C. Facchini1, S. Fuzzi1, P. Cristofanelli1, A. Marinoni1, P. Bonasoni1, M. Chiari2, G. Calzolai2, S. Canepari3, and C. Perrino4
1Institute of Atmospheric Sciences and Climate, National Research Council, Bologna, 40129, Italy
2Italian National Institute for Nuclear Physics, Florence section, Sesto Fiorentino, 50019, Italy
3University of Rome "La Sapienza", Chemistry Department, Rome, 00185, Italy
4C.N.R. Institute of Atmospheric Pollution, Monterotondo St., Rome, 00015, Italy

Abstract. Continuous measurements of physical and chemical properties at the Mt. Cimone GAW-WMO Global Station (2165 m a.s.l.) allowed the detection of the volcanic aerosol plume resulting from the Eyjafjallajökull eruption of spring 2010. The event affected the site after a transport over a distance of more than 3000 km. Two main transport episodes were detected during the eruption period, showing a volcanic fingerprint discernible against the free tropospheric background conditions typical of the site, the first from 19 to 21 April and the second from 18 to 20 May 2010. The paper reports the modification of aerosol characteristics observed during the two episodes, both characterized by an abrupt increase in fine and, especially, coarse mode particle number.

Analysis of major, minor and trace elements by different analytical techniques (Ionic Chromatography, PIXE-PIGE and ICP-MS) were performed on aerosols collected by ground level discrete sampling. The resulting database allows the characterization of aerosol chemical composition during the volcanic plume transport and in background conditions. During the passage of the volcanic plume, the fine fraction was dominated by sulphates, denoting the secondary origin of this mode, mainly resulting from in-plume oxidation of volcanic SO2. By contrast, the coarse fraction was characterized by increased concentration of numerous elements of crustal origin, such as Fe, Ti, Mn, Ca, Na, and Mg, which enter the composition of silicate minerals. Data analysis of selected elements (Ti, Al, Fe, Mn) allowed the estimation of the volcanic plume's contribution to total PM10, resulting in a local enhancement of up to 9.5 μg m-3, i.e. 40% of total PM10, on 18 May, which was the most intense of the two episodes. These results appear significant, especially in the light of the huge distance of Mt. Cimone from the source, confirming the widespread diffusion of the Eyjafjallajokull ashes over Europe.


Citation: Sandrini, S., Giulianelli, L., Decesari, S., Facchini, M. C., Fuzzi, S., Cristofanelli, P., Marinoni, A., Bonasoni, P., Chiari, M., Calzolai, G., Canepari, S., and Perrino, C.: In-situ physical and chemical characterization of the Eyjafjallajökull aerosol plume in the free troposphere over Italy, Atmos. Chem. Phys. Discuss., 13, 20195-20238, doi:10.5194/acpd-13-20195-2013, 2013.
 
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