Atmos. Chem. Phys. Discuss., 13, 16775-16830, 2013
www.atmos-chem-phys-discuss.net/13/16775/2013/
doi:10.5194/acpd-13-16775-2013
© Author(s) 2013. This work is distributed
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Quantifying the contributions of natural emissions to ozone and total fine PM concentrations in the Northern Hemisphere
A. Zare1,2,3, J. H. Christensen2, A. Gross2,4, P. Irannejad1, M. Glasius3, and J. Brandt2
1Institute of Geophysics, University of Tehran, Iran
2Department of Environmental Science, Aarhus University, Denmark
3Department of Chemistry and iNANO, Aarhus University, Denmark
4AU Herning, Aarhus University, Denmark

Abstract. Accurate estimates of emissions from natural sources are needed for reliable predictions of ozone and fine particulate matter (PM2.5) using air quality models. In this study, the large-scale atmospheric chemistry transport model, DEHM (the Danish Eulerian Hemispheric Model) is further developed, evaluated and applied to study and quantify the contributions of natural emissions of VOCs, NOx, NH3, SO2, CH4, PM, CO and sea salt to the concentration of ozone and formation of PM2.5 for the year 2006. Natural source categories adopted in the recent model are vegetation, lightning, soils, wild animals and oceans. In this study, the model has been further developed to include more biogenic volatile organic compounds (BVOCs) and to implement a scheme for secondary organic aerosol as well as an updated description of sea-salt emissions. Our simulations indicate that at Northern Hemisphere the contribution from natural emissions to the average annual ozone concentrations over land is between 4–30 ppbV. Among the natural emissions, BVOCs are found to be the most significant contributors to ozone formation, enhancing the average ozone concentration by about 11% over the land areas of the Northern Hemisphere. The relative contribution of all the natural emissions to ozone is found to be highest in the northern part of South America by about 42%. Similarly, the highest contribution of all the natural sources to total fine particles over land is found to be in South America by about 74% and sea-salt aerosols demonstrated to play the most important role. However, over the rest of regions in the model domain the largest contribution from the natural sources to PM2.5 is due to wildfires. The contribution from natural emissions to the mean PM2.5 concentration over the land areas in the model domain is about 34%.

Citation: Zare, A., Christensen, J. H., Gross, A., Irannejad, P., Glasius, M., and Brandt, J.: Quantifying the contributions of natural emissions to ozone and total fine PM concentrations in the Northern Hemisphere, Atmos. Chem. Phys. Discuss., 13, 16775-16830, doi:10.5194/acpd-13-16775-2013, 2013.
 
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