Atmos. Chem. Phys. Discuss., 13, 14163-14193, 2013
www.atmos-chem-phys-discuss.net/13/14163/2013/
doi:10.5194/acpd-13-14163-2013
© Author(s) 2013. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Photochemical chlorine and bromine activation from artificial saline snow
S. N. Wren, D. J. Donaldson, and J. P. D. Abbatt
Department of Chemistry, University of Toronto, 80 St. George St., Toronto, ON, M5S 3H6, Canada

Abstract. The activation of reactive halogen species – particularly Cl2 – from sea ice and snow surfaces is not well understood. In this study, we used a photochemical snow reactor coupled to a chemical ionization mass spectrometer to investigate the production of Br2, BrCl and Cl2 from NaCl/NaBr-doped artificial snow samples. At temperatures above the NaCl-water eutectic, illumination of samples (λ > 310 nm) in the presence of gas phase O3 led to the accelerated release of Br2, BrCl and the release of Cl2 in a process that was significantly enhanced by acidity, high surface area and additional gas phase Br2. Cl2 production was only observed when both light and ozone were present. The total halogen release depended on [O3] and pre-freezing [NaCl]. Our observations support a "halogen explosion" mechanism occurring within the snowpack which is initiated by heterogeneous oxidation, and propagated by Br2 or BrCl photolysis and by recycling of HOBr and HOCl into the snowpack. Our study implicates an important role for active chemistry occurring within the interstitial air of aged (i.e., acidic) snow for halogen activation at polar sunrise.

Citation: Wren, S. N., Donaldson, D. J., and Abbatt, J. P. D.: Photochemical chlorine and bromine activation from artificial saline snow, Atmos. Chem. Phys. Discuss., 13, 14163-14193, doi:10.5194/acpd-13-14163-2013, 2013.
 
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