Atmos. Chem. Phys. Discuss., 13, 1247-1277, 2013
www.atmos-chem-phys-discuss.net/13/1247/2013/
doi:10.5194/acpd-13-1247-2013
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Seasonal and spatial variability of the organic matter-to-organic carbon mass ratios in Chinese urban organic aerosols and a first report of high correlations between aerosol oxalic acid and zinc
L. Xing1, T.-M. Fu1, J. J. Cao2, S. C. Lee3, G. H. Wang2, K. F. Ho4, M.-C. Cheng5, C.-F. You5, and T. J. Wang6
1Department of Atmospheric and Oceanic Sciences and Laboratory for Climate and Ocean-Atmosphere Studies, School of Physics, Peking University, Beijing, 100871, China
2State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an, 710075, China
3Research Centre of Urban Environmental Technology and Management, Department of Civil and Structural Engineering, Hong Kong Polytechnic University, Hong Kong, China
4School of Public Health and Primary Care, The Chinese University of Hong Kong, Hong Kong, China
5Department of Earth Sciences, National Cheng Kung University, Tainan 701, Taiwan, China
6School of Atmospheric Sciences, Nanjing University, Nanjing, 210093, China

Abstract. We calculated the organic matter to organic carbon mass ratios (OM/OC mass ratios) in PM2.5 collected from 14 Chinese cities during summer and winter of 2003 and analyzed the causes for their seasonal and spatial variability. The OM/OC mass ratios were calculated two ways. Using a mass balance method, the calculated OM/OC mass ratios averaged 1.92 ± 0.39 yr-round, with no significant seasonal or spatial variation. The second calculation was based on chemical species analyses of the organic compounds extracted from the PM2.5 samples using dichloromethane/methanol and water. The calculated OM/OC mass ratio in summer was relatively high (1.75 ± 0.13) and spatially-invariant, due to vigorous photochemistry and secondary OA production throughout the country. The calculated OM/OC mass ratio in winter (1.59 ± 0.18) was significantly lower than that in summer, with lower values in northern cities (1.51 ± 0.07) than in southern cities (1.65 ± 0.15). This likely reflects the wider usage of coal for heating purposes in northern China in winter, in contrast to the larger contributions from biofuel and biomass burning in southern China in winter. On average, organic matters constituted 36% and 34% of Chinese urban PM2.5 mass in summer and winter, respectively. We reported, for the first time, high correlations between Zn and oxalic acid in Chinese urban aerosols in summer. This is consistent with the formation of stable Zn oxalate complex in the aerosol phase previously proposed by Furukawa and Takahashi (2011). We found that many other dicarboxylic acids were also highly correlated with Zn in the summer Chinese urban aerosol samples, suggesting that they may also form stable organic complexes with Zn. Such formation may have profound implications for the atmospheric abundance and hygroscopic property of aerosol dicarboxylic acids.

Citation: Xing, L., Fu, T.-M., Cao, J. J., Lee, S. C., Wang, G. H., Ho, K. F., Cheng, M.-C., You, C.-F., and Wang, T. J.: Seasonal and spatial variability of the organic matter-to-organic carbon mass ratios in Chinese urban organic aerosols and a first report of high correlations between aerosol oxalic acid and zinc, Atmos. Chem. Phys. Discuss., 13, 1247-1277, doi:10.5194/acpd-13-1247-2013, 2013.
 
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