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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-12-7879-2012</article-id>
<title-group>
<article-title>Glass formation and unusual hygroscopic growth of iodic acid solution droplets with relevance for iodine oxide particles in the coastal marine boundary layer</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Murray</surname>
<given-names>B. J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Haddrell</surname>
<given-names>A. E.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Peppe</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Davies</surname>
<given-names>J. F.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Reid</surname>
<given-names>J. P.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>O&apos;Sullivan</surname>
<given-names>D.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Price</surname>
<given-names>H. C.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kumar</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Saunders</surname>
<given-names>R. W.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Plane</surname>
<given-names>J. M. C.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Umo</surname>
<given-names>N. S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wilson</surname>
<given-names>T. W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>School of Earth and Environment, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK</addr-line>
</aff>
<pub-date pub-type="epub">
<day>20</day>
<month>03</month>
<year>2012</year>
</pub-date>
<volume>12</volume>
<issue>3</issue>
<fpage>7879</fpage>
<lpage>7908</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<abstract>
<p>Iodine oxide particles are known to nucleate in the marine boundary layer
where gas phase molecular iodine and organoiodine species are produced by
macroalgae. There has been some debate over the chemical identity of these
particles. Hygroscopic measurements have been used to infer that they are
composed of insoluble I&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;4&lt;/sub&gt;, while elemental analysis of laboratory
generated particles suggests soluble I&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; or its hydrated form
iodic acid, HIO&lt;sub&gt;3&lt;/sub&gt; (I&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; · H&lt;sub&gt;2&lt;/sub&gt;O). In this paper we
explore the response of super-micron sized aqueous iodic acid solution
droplets to varying humidity using both Raman microscopy and single particle
electrodynamic traps. These measurements reveal that the propensity of an
iodic acid solution droplet to crystallise is negligible on drying to ~0% relative humidity (RH). On applying mechanical pressure to these
droplets they shatter in a manner consistent with an ultra-viscous liquid or
a brittle glass, but subsequent water uptake between 10 and 20% RH causes
their viscosity to reduce sufficiently that the cracked droplets flow and
merge. The persistence of iodic acid solution in an amorphous state, rather
than a crystalline state, suggests they will more readily accommodate other
condensable material and are therefore more likely to grow to sizes where
they may serve as cloud condensation nuclei. On increasing the humidity to
~90% the mass of the droplets only increases by ~20% with
a corresponding increase in radius of only ~6 %, which is remarkably small
for a highly soluble material. We suggest that the small growth factor of
aqueous iodic acid solution droplets is consistent with the small aerosol
growth factors observed in field experiments.</p>
</abstract>
<counts><page-count count="30"/></counts>
</article-meta>
</front>
<body/>
<back>
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