Atmos. Chem. Phys. Discuss., 12, 7617-7675, 2012
www.atmos-chem-phys-discuss.net/12/7617/2012/
doi:10.5194/acpd-12-7617-2012
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under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
A model study of the Eastern Mediterranean ozone levels during the hot summer of 2007
Ø. Hodnebrog1, S. Solberg2, F. Stordal1, T. M. Svendby2, D. Simpson3,4, M. Gauss3, A. Hilboll5, G. G. Pfister6, S. Turquety7, A. Richter5, J. P. Burrows5, and H. A. C. Denier van der Gon8
1Department of Geosciences, University of Oslo, Oslo, Norway
2Norwegian Institute for Air Research, Kjeller, Norway
3Norwegian Meteorological Institute, Oslo, Norway
4Dept. Earth and Space Sciences, Chalmers University of Technology, Göteborg, Sweden
5Institute of Environmental Physics, University of Bremen, Bremen, Germany
6Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, CO, USA
7Laboratoire de Météorologie Dynamique/IPSL, UPMC Univ. Paris 06, Paris, France
8TNO, Business unit Environment, Health and Safety, Utrecht, The Netherlands

Abstract. The hot summer of 2007 in Southeast Europe has been studied using two regional atmospheric chemistry models; WRF-Chem and EMEP MSC-W. The region was struck by three heat waves and a number of forest fire episodes, greatly affecting air pollution levels. We have focused on ozone and its precursors using state-of-the-art inventories for anthropogenic, biogenic and forest fire emissions. The models have been evaluated against measurement data, and processes leading to ozone formation have been quantified. Heat wave episodes are projected to occur more frequently in a future climate, and therefore this study also makes a contribution to climate change research.

The plume from the Greek forest fires in August 2007 is clearly seen in satellite observations of CO and NO2 columns, showing extreme levels of CO in and downwind of the fires. Model simulations reflect the location and influence of the fires relatively well, but the modelled magnitude of CO in the plume core is too low. Most likely, this is caused by underestimation of CO in the emission inventories, suggesting that the CO/NOx ratios of fire emissions should be re-assessed. Moreover, higher maximum values are seen in WRF-Chem than in EMEP MSC-W, presumably due to differences in plume rise altitudes as the first model emits a larger fraction of the fire emissions in the lowermost model layer. The model results are also in fairly good agreement with surface ozone measurements.

Biogenic VOC emissions reacting with anthropogenic NOx emissions are calculated to contribute significantly to the levels of ozone in the region, but the magnitude and geographical distribution depend strongly on the model and biogenic emission module used. During the July and August heat waves, ozone levels increased substantially due to a combination of forest fire emissions and the effect of high temperatures. We found that the largest temperature impact on ozone was through the temperature dependence of the biogenic emissions, closely followed by the effect of decreased dry deposition. The impact of high temperatures on the ozone chemistry was much lower. The results suggest that forest fire emissions, and the temperature effect on biogenic emissions and dry deposition, will potentially lead to substantial ozone increases in a warmer climate.


Citation: Hodnebrog, Ø., Solberg, S., Stordal, F., Svendby, T. M., Simpson, D., Gauss, M., Hilboll, A., Pfister, G. G., Turquety, S., Richter, A., Burrows, J. P., and Denier van der Gon, H. A. C.: A model study of the Eastern Mediterranean ozone levels during the hot summer of 2007, Atmos. Chem. Phys. Discuss., 12, 7617-7675, doi:10.5194/acpd-12-7617-2012, 2012.
 
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