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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-12-28993-2012</article-id>
<title-group>
<article-title>Impact of aging mechanism on model simulated carbonaceous aerosols</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Huang</surname>
<given-names>Y.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wu</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dubey</surname>
<given-names>M. K.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>French</surname>
<given-names>N. H. F.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Geological and Mining Engineering and Sciences, Michigan Technological University, Houghton, MI 49931, USA</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Atmospheric Science Program, Department of Geological and Mining Engineering and Sciences, Department of Civil and Environmental Engineering, Michigan Technological University, Houghton, MI 49931, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Earth System Observations, Los Alamos National Laboratory, Los Alamos, NM 87545, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Michigan Tech Research Institute, Michigan Technological University, Ann Arbor, MI 48105, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>09</day>
<month>11</month>
<year>2012</year>
</pub-date>
<volume>12</volume>
<issue>11</issue>
<fpage>28993</fpage>
<lpage>29023</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/12/28993/2012/acpd-12-28993-2012.html">This article is available from http://www.atmos-chem-phys-discuss.net/12/28993/2012/acpd-12-28993-2012.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/12/28993/2012/acpd-12-28993-2012.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/12/28993/2012/acpd-12-28993-2012.pdf</self-uri>
<abstract>
<p>Carbonaceous aerosols that include organic carbon and black carbon, have significant implications for both climate and air
      quality. In the current global climate or chemical transport models, a simplified hydrophobic to hydrophilic conversion
      lifetime for carbonaceous aerosol (τ) is generally assumed, which is usually around 1 day. Based on results from
      recent chamber studies, we implemented a new detailed aging mechanism for carbonaceous aerosols in a chemical transport model
      (GEOS-Chem) where τ is affected by local conditions such as O&lt;sub&gt;3&lt;/sub&gt; concentration and humidity. The simulated τ
      exhibits large spatial and temporal variation with the global average calculated to be 4.3 days. The longest τ
      (up to 40 days for the Amazon forests) are found in the tropical areas, reflecting the low ozone concentration and high
      humidity there. The conversion lifetime generally decreases with altitude due to increases in ozone concentration and decreases
      in water vapor concentration. The updated aging mechanism has significant implications for model simulations of carbonaceous
      aerosols and improves the comparison to observations of carbonaceous aerosols. The strongest effects are found for the tropical
      regions and upper troposphere where the model simulated concentrations of black carbon and organic carbon increase by up to
      0.16 &amp;mu;g C m&lt;sup&gt;&amp;minus;3&lt;/sup&gt; and 0.67 &amp;mu;g C m&lt;sup&gt;&amp;minus;3&lt;/sup&gt;, respectively. This updated aging mechanism also leads to
      increases in model calculated global burden of black carbon and organic carbon by 31% and 17%, respectively. In
      addition, sensitivity studies show that the estimated continental outflow of carbonaceous aerosols would significantly increase
      with the updated aging mechanism.</p>
</abstract>
<counts><page-count count="31"/></counts>
</article-meta>
</front>
<body/>
<back>
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