Atmos. Chem. Phys. Discuss., 12, 28733-28764, 2012
© Author(s) 2012. This work is distributed
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Stratospheric loss and atmospheric lifetimes of CFC-11 and CFC-12 derived from satellite observations
K. Minschwaner1, L. Hoffmann2, A. Brown3, M. Riese4, R. Müller4, and P. F. Bernath3,5
1Department of Physics, New Mexico Institute of Mining and Technology, Socorro, USA
2Jülich Supercomputing Centre (JSC), Forschungszentrum Jülich, Germany
3Department of Chemistry, University of York, UK
4Institute of Energy and Climate Research (IEK-7), Forschungszentrum Jülich, Germany
5Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, VA, USA

Abstract. The lifetimes of CFC-11 and CFC-12 have been evaluated using global observations of their stratospheric distributions from satellite-based instruments between the period 1992 and 2010. The CFC data sets are from the Cryogen Limb Array Etalon Spectrometer (CLAES), the Cryogenic Infrared Spectrometers and Telescopes for the Atmosphere (CRISTA-1 and CRISTA-2), the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), and the Atmospheric Chemistry Experiment (ACE). Stratospheric loss rates were calculated using an ultraviolet radiative transfer code with updated cross section and solar irradiance data. Mean steady state lifetimes based on these observations are 50.3 ± 16.8 yr for CFC-11 and 106.9 ± 21.7 yr for CFC-12, which are in reasonable agreement with the most recent WMO Ozone Assessment recommendations but are somewhat longer by 12% and 7%, respectively. There are two major sources of error in calculating lifetimes using this method. One error source is due to uncertainties in tropical stratospheric measurements, particularly for CFC-11. Another large contribution to the error arises from uncertainties in the penetration of solar ultraviolet radiation at wavelengths between 185 and 220 nm, primarily in the tropical stratosphere between 20 and 35 km altitude.

Citation: Minschwaner, K., Hoffmann, L., Brown, A., Riese, M., Müller, R., and Bernath, P. F.: Stratospheric loss and atmospheric lifetimes of CFC-11 and CFC-12 derived from satellite observations, Atmos. Chem. Phys. Discuss., 12, 28733-28764, doi:10.5194/acpd-12-28733-2012, 2012.
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