Atmos. Chem. Phys. Discuss., 12, 24469-24499, 2012
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Re-evaluation of the lifetimes of the major CFCs and CH3CCl3 using atmospheric trends
M. Rigby1,2, R. G. Prinn2, S. O'Doherty1, S. A. Montzka3, A. McCulloch1, C. M. Harth4, J. Mühle4, P. K. Salameh4, R. F. Weiss4, D. Young1, P. G. Simmonds1, B. D. Hall3, G. S. Dutton3, D. Nance3, D. J. Mondeel3, J. W. Elkins3, P. B. Krummel5, L. P. Steele5, and P. J. Fraser5
1School of Chemistry, University of Bristol, Bristol, UK
2Center for Global Change Science, Massachusetts Institute of Technology, Cambridge, MA, USA
3NOAA Earth System Research Laboratory, Boulder, CO, USA
4Scripps Institution of Oceanography, University of California at San Diego, La Jolla, CA, USA
5Centre for Australian Weather and Climate Research, CSIRO Marine and Atmospheric Research, Aspendale, Victoria, Australia

Abstract. Since the Montreal Protocol on substances that deplete the ozone layer and its amendments came into effect, growth rates of the major ozone depleting substances (ODS), particularly CFC-11, -12 and -113 and CH3CCl3, have declined markedly, paving the way for global stratospheric ozone recovery. Emissions have now fallen to relatively low levels, therefore the rate at which this recovery occurs will depend largely on the atmospheric lifetime of these compounds. The first ODS measurements began in the early 1970s along with the first lifetime estimates calculated by considering their atmospheric trends. We now have global mole fraction records spanning multiple decades, prompting this lifetime re-evaluation. Using surface measurements from the Advanced Global Atmospheric Gases Experiment (AGAGE) and the National Oceanic and Atmospheric Administration Global Monitoring Division (NOAA GMD) from 1978 to 2011, we estimated the lifetime of CFC-11, CFC-12, CFC-113 and CH3CCl3 using a multi-species inverse method. The CFC-11 lifetime of 45 yr, currently recommended in the World Meteorological Organisation (WMO) Scientific Assessment of Ozone Depletion, lies at the lower uncertainty bound of our estimates which are 524066 yr (1-sigma uncertainty) when AGAGE data were used, and 504066 yr when the NOAA network data were used. Our derived lifetime for CFC-113 is higher than the WMO estimates of 85 yr (10488123 using AGAGE, 10387122 using NOAA). Our estimates of the lifetime of CFC-12 and CH3CCl3 agree well with other recent estimates being 10885137 and 10484135 yr (CFC-12, AGAGE and NOAA, respectively) and and yr (CH3CCl3, AGAGE and NOAA, respectively).

Citation: Rigby, M., Prinn, R. G., O'Doherty, S., Montzka, S. A., McCulloch, A., Harth, C. M., Mühle, J., Salameh, P. K., Weiss, R. F., Young, D., Simmonds, P. G., Hall, B. D., Dutton, G. S., Nance, D., Mondeel, D. J., Elkins, J. W., Krummel, P. B., Steele, L. P., and Fraser, P. J.: Re-evaluation of the lifetimes of the major CFCs and CH3CCl3 using atmospheric trends, Atmos. Chem. Phys. Discuss., 12, 24469-24499, doi:10.5194/acpd-12-24469-2012, 2012.
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