Atmos. Chem. Phys. Discuss., 12, 23333-23401, 2012
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Long term measurements of aerosol optical properties at a pristine forest site in Amazonia
L. V. Rizzo1, P. Artaxo2, T. Müller3, A. Wiedensohler3, M. Paixão3, G. G. Cirino4, A. Arana2, E. Swietlicki5, P. Roldin5, E. O. Fors5, K. T. Wiedemann6, L. S. M. Leal4, and M. Kulmala7
1Department of Earth and Exact Sciences, Institute of Environmental, Chemical and Pharmaceutics Sciences, Federal University of São Paulo, São Paulo, Brazil
2Department of Applied Physics, Institute of Physics, University of São Paulo, São Paulo, Brazil
3Leibniz Institute for Tropospheric Research, Leipzig, Germany
4National Institute for Amazonian Research (INPA), Manaus, Brazil
5Division of Nuclear Physics, Physics Institute, Lund University, Lund, Sweden
6Division of Engineering and Applied Science/Department of Earth and Planetary Science, Harvard University, Cambridge, USA
7Department of Physical Sciences, Division of Atmospheric Sciences, University of Helsinki, Helsinki, Finland

Abstract. A long term experiment was conducted in a pristine area in the Amazon forest, with continuous in situ measurements of aerosol optical properties between February 2008 and April 2011, comprising, to our knowledge, the longest database ever in Amazonia. Two types of aerosol particles, with significantly different optical properties were identified: coarse mode predominant biogenic aerosols in the wet season (January–June), naturally released by the forest metabolism, and fine mode dominated biomass burning aerosols in the dry season (July–December), transported from regional fires. Dry particle median scattering coefficients at the wavelength of 550 nm increased from 6.3 Mm−1 to 22 Mm−1, whereas absorption at 637 nm increased from 0.5 Mm−1 to 2.8 Mm−1 from wet to dry season. Most of the scattering in the dry season was attributed to the predominance of fine mode particles (40–80% of PM10 mass), while the enhanced absorption coefficients are attributed to the presence of light absorbing aerosols from biomass burning. As both scattering and absorption increased in the dry season, the single scattering albedo (SSA) did not show a significant seasonal variability, in average 0.86 ± 0.08 at 637 nm for dry particles. Measured particle optical properties were used to estimate the aerosol forcing efficiency at the top of the atmosphere. Results indicate that in this pristine forest site the radiative balance was dominated by the cloud cover, or, in other words, the aerosol indirect effect predominated over the direct effect, particularly in the wet season. Due to the high cloud fractions, the aerosol forcing efficiency was below −3.5 W m−2 in 70% of the wet season days and in 46% of the dry season days. These values are lower than the ones reported in the literature, which are based on remote sensing data. Besides the seasonal variation, the influence of external aerosol sources was observed occasionally. Periods of influence of the Manaus urban plume were detected, characterized by a consistent increase on particle scattering (factor 2.5) and absorption coefficients (factor 5). Episodes of biomass burning and mineral dust particles advection from Africa were observed between January and April, characterized by enhanced concentrations of fine mode (PM2.0), crustal elements (Al, Si, Ti, Fe) and potassium. During these episodes, median particle absorption coefficients increased by a factor of 2, whereas median SSA values decreased by 7%, in comparison to wet season conditions.

Citation: Rizzo, L. V., Artaxo, P., Müller, T., Wiedensohler, A., Paixão, M., Cirino, G. G., Arana, A., Swietlicki, E., Roldin, P., Fors, E. O., Wiedemann, K. T., Leal, L. S. M., and Kulmala, M.: Long term measurements of aerosol optical properties at a pristine forest site in Amazonia, Atmos. Chem. Phys. Discuss., 12, 23333-23401, doi:10.5194/acpd-12-23333-2012, 2012.
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