Atmos. Chem. Phys. Discuss., 12, 20631-20671, 2012
www.atmos-chem-phys-discuss.net/12/20631/2012/
doi:10.5194/acpd-12-20631-2012
© Author(s) 2012. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Chemical characterization and stable carbon isotopic composition of particulate polycyclic aromatic hydrocarbons issued from combustion of 10 Mediterranean woods
A. Guillon1,2, K. Le Ménach1,2, P.-M. Flaud1,2, N. Marchand3, H. Budzinski1,2, and E. Villenave1,2
1CNRS, Laboratoire EPOC (Environnements et Paléoenvironnements Océaniques et Continentaux), UMR5805, Equipe LPTC (Laboratoire de Physico- et Toxico-Chimie de l'Environnement, 33400 Talence, France
2Univ. Bordeaux, EPOC, UMR5805, 33400 Talence, France
3Universités d'Aix-Marseille-CNRS, UMR6264, Laboratoire Chimie Provence, Equipe Instrumentation et Réactivité Atmosphérique, Marseille, 13331, France

Abstract. The objectives of this study were to characterize polycyclic aromatic hydrocarbons from particulate matter emitted during wood combustion and to determine, for the first time, the isotopic signature of PAHs from nine wood species and Moroccan coal from the Mediterranean Basin. In order to differentiate sources of particulate-PAHs, molecular and isotopic measurements of PAHs were performed on the set of wood samples for a large panel of compounds. Molecular profiles and diagnostic ratios were measured by gas chromatography coupled with a mass spectrometer (GC/MS) and molecular isotopic compositions (δ13C) of particulate-PAHs were determined by gas chromatography/combustion/isotope ratio mass spectrometry (GC/C/IRMS). Wood species present similar molecular profiles with benz(a)anthracene and chrysene as dominant PAHs, whereas levels of concentrations range from 1.8 to 11.4 mg g−1 OC (sum of PAHs). Diagnostic ratios are consistent with reference ratios from literature but are not sufficient to differentiate the different species of woods. Concerning isotopic methodology, PAH molecular isotopic compositions are specific for each species and contrary to molecular fingerprints, significant variations of δ13C are observed for the panel of PAHs. This work allows differentiating wood combustion from others origins of particulate matter (vehicular exhaust) using isotopic measurements (with δ13CPAH = −28.7 to −26.6‰) but also confirms the necessity to investigate source characterisation at the emission in order to help and complete source assessment models. These first results on woodburnings will be useful for the isotopic approach of source tracking.

Citation: Guillon, A., Le Ménach, K., Flaud, P.-M., Marchand, N., Budzinski, H., and Villenave, E.: Chemical characterization and stable carbon isotopic composition of particulate polycyclic aromatic hydrocarbons issued from combustion of 10 Mediterranean woods, Atmos. Chem. Phys. Discuss., 12, 20631-20671, doi:10.5194/acpd-12-20631-2012, 2012.
 
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