Atmos. Chem. Phys. Discuss., 12, 18671-18713, 2012
www.atmos-chem-phys-discuss.net/12/18671/2012/
doi:10.5194/acpd-12-18671-2012
© Author(s) 2012. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Interrelated variations of O3, CO and deep convection in the tropical/subtropical upper troposphere observed by the Aura Microwave Limb Sounder (MLS) during 2004–2011
N. J. Livesey1, J. A. Logan2, M. L. Santee1, J. W. Waters1, R. M. Doherty3, W. G. Read1, L. Froidevaux1, and J. H. Jiang1
1Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
2School of Engineering and Applied Sciences, Harvard University, Cambridge, USA
3School of GeoSciences, The University of Edinburgh, Edinburgh, Scotland

Abstract. The interrelated geographical and temporal variability seen in more than seven years of tropical and subtropical upper tropospheric (215 hPa) ozone, carbon monoxide and cloud ice water content (IWC) observations by the Aura Microwave Limb Sounder (MLS) are presented. Observed ozone abundances and their variability (geographical and temporal) agree to within 10–15 ppbv with records from sonde observations. MLS complements these (and other) observations with global coverage and simultaneous measurements of related parameters. Previously-reported phenomena such as the ozone "wave one" feature are clearly seen in the MLS observations, as is a double peak in ozone abundance over tropical East Africa, with enhanced abundances in both May to June and September to November. While repeatable seasonal cycles are seen in many regions, they are often accompanied by significant interannual variability. Ozone seasonal cycles in the southern tropics and subtropics tend to be more distinct (i.e., annually repeatable) than in the northern. By contrast, carbon monoxide shows distinct seasonal cycles in many northern subtropical regions, notably from India to the Eastern Pacific. Deep convection (as indicated by large values of IWC) is typically associated with reductions in upper tropospheric ozone. Convection over polluted regions is seen to significantly enhance upper tropospheric carbon monoxide. While some regions show statistically significant correlations among ozone, carbon monoxide and IWC, simple correlations fall well short of accounting for the observed variability. The observed interrelated variations and metrics of annual and interannual variability described here represent a new resource for validation of atmospheric chemistry models.

Citation: Livesey, N. J., Logan, J. A., Santee, M. L., Waters, J. W., Doherty, R. M., Read, W. G., Froidevaux, L., and Jiang, J. H.: Interrelated variations of O3, CO and deep convection in the tropical/subtropical upper troposphere observed by the Aura Microwave Limb Sounder (MLS) during 2004–2011, Atmos. Chem. Phys. Discuss., 12, 18671-18713, doi:10.5194/acpd-12-18671-2012, 2012.
 
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