Atmos. Chem. Phys. Discuss., 12, 14247-14268, 2012
www.atmos-chem-phys-discuss.net/12/14247/2012/
doi:10.5194/acpd-12-14247-2012
© Author(s) 2012. This work is distributed
under the Creative Commons Attribution 3.0 License.
Review Status
This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Technical Note: Synthesis of isoprene atmospheric oxidation products: isomeric epoxydiols and the rearrangement products cis- and trans-3-methyl-3,4-dihydroxytetrahydrofuran
Z. Zhang, Y.-H. Lin, H. Zhang, J. D. Surratt, L. M. Ball, and A. Gold
Department of Environmental Sciences and Engineering, Gillings School of Global Public Health, The University of North Carolina at Chapel Hill, NC, 27599-7431, USA

Abstract. Isoprene epoxydiol (IEPOX) isomers are key gas-phase intermediates of isoprene atmospheric oxidation. Secondary organic aerosols derived from such intermediates have important impacts on air quality and health. We report here convergent and unambiguous pathways developed for the synthesis of isomeric IEPOX species and the rearrangement products cis- and trans-3-methyl-3,4-dihydroxytetrahydrofuran in good yield. The availability of such compounds is necessary to expedite research on isoprene atmospheric oxidation mechanisms and subsequent aerosol formation as well as the toxicological properties of the aerosols.

Citation: Zhang, Z., Lin, Y.-H., Zhang, H., Surratt, J. D., Ball, L. M., and Gold, A.: Technical Note: Synthesis of isoprene atmospheric oxidation products: isomeric epoxydiols and the rearrangement products cis- and trans-3-methyl-3,4-dihydroxytetrahydrofuran, Atmos. Chem. Phys. Discuss., 12, 14247-14268, doi:10.5194/acpd-12-14247-2012, 2012.
 
Search ACPD
Discussion Paper
XML
Citation
Final Revised Paper
Share