Atmos. Chem. Phys. Discuss., 11, 7659-7691, 2011
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Mass and chemical composition of size-segregated aerosols (PM1, PM2.5, PM10) over Athens, Greece: local versus regional sources
C. Theodosi1, G. Grivas2, P. Zarmpas1, A. Chaloulakou2, and N. Mihalopoulos1
1Environmental Chemical Processes Laboratory, Department of Chemistry, University of Crete, P.O. Box 2208, 71003 Heraklion, Greece
2School of Chemical engineering, National Technical University of Athens, Heroon Polytechniou 9, GR-15780 Zografou, Athens, Greece

Abstract. To identify the relative contribution of local versus regional sources of particulate matter (PM) in the Greater Athens Area (GAA), simultaneous mass and chemical composition measurements of size segregated particulate matter (PM: PM1, PM2.5 and PM10) were carried out from September 2005 to August 2006 at three locations: one urban (Goudi, Central Athens) and one suburban (Lykovrissi, Athens) in GAA and the third in a regional background site (Finokalia, Crete).

The two stations in GAA exceeded the EU-legislated PM10 limit values, both in terms of annual average (59.0 and 53.6 μg m−3 for Lykovrissi and Goudi, respectively) and of 24-h value, while the concentration levels at the remote site of Finokalia indicated an elevated background. High levels of PM2.5 and PM1 were also found at all locations (23.5 and 18.6 for Lykovrissi, while 29.4 and 20.2 μg m−3 for Goudi, respectively).

Significant correlations were observed between same PM fractions at both GAA sites indicating important spatial homogeneity within GAA. During the warm season, the PM1 ratio between the GAA and the background site ranged from 1.1 to 1.3. On the other hand this ratio was significantly higher (1.6–1.7) during the cold season highlighting the role of long-range transport and local sources during the warm and cold seasons respectively. Similar seasonal and geographical patterns were observed for nss-SO42−, a secondary compound characteristic of regional sources, confirming the above hypothesis.

Regarding the coarse fraction no such seasonal trend was observed for both GAA sites with their ratio (GAA site/Finokalia) being higher than 2 indicating significant contribution from local sources such as road dust and/or constructions as confirmed by Ca2+ measurements.

Chemical speciation data showed that on a yearly basis, ionic and crustal mass represent up to 78% of the gravimetrically determined mass for PM10 samples in GAA. The unidentified mass might be attributed to organic carbon (OC) and elemental carbon (EC), in agreement with the results reported by earlier studies in central Athens.

The contribution of local sources at both GAA sites was also estimated by considering mass and chemical composition measurements at Finokalia as representative of the regional background. Carbonaceous material, Particulate Organic Matter (POM) and EC, seemed to be the main contributor of the local PM mass within GAA (up to 62% in PM1). Dust from local sources (mainly resuspension) contributed also significantly to the local PM10 mass (up to 33%).

Citation: Theodosi, C., Grivas, G., Zarmpas, P., Chaloulakou, A., and Mihalopoulos, N.: Mass and chemical composition of size-segregated aerosols (PM1, PM2.5, PM10) over Athens, Greece: local versus regional sources, Atmos. Chem. Phys. Discuss., 11, 7659-7691, doi:10.5194/acpd-11-7659-2011, 2011.
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