Atmos. Chem. Phys. Discuss., 11, 31983-32002, 2011
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Atmospheric sulphuric acid and neutral cluster measurements using CI-APi-TOF
T. Jokinen1, M. Sipilä1, H. Junninen1, M. Ehn2, G. Lönn1, J. Hakala1, T. Petäjä1, R. L. Mauldin III1, M. Kulmala1, and D. R. Worsnop1,3,4,5
1Department of Physics, P.O. Box 64, 00014, University of Helsinki, Finland
2Institute for Energy and Climate Research, Forschungszentrum Jülich, Germany
3University of Eastern Finland, P.O. Box 1627, 70211 Kuopio, Finland
4Finnish Meteorological Institute, 00880 Helsinki, Finland
5Aerodyne Research Inc., Billerica, MA 01821, USA

Abstract. The first ambient measurements using nitrate ion based Chemical Ionization with the Atmospheric Pressure interface Time-Of-Flight mass spectrometer (CI-APi-TOF) for sulphuric acid and neutral cluster detection are presented. We have found CI-APi-TOF a highly stable and sensitive tool for molecular sulphuric acid detection. The lowest limit of detection for sulphuric acid was determined to be 3 × 104 molecules cm−3 for two hour averaging. Signals from sulphuric acid clusters up to tetramer accompanied by ammonia were also obtained but these were found to result from naturally charged clusters formed by ion induced clustering in the atmosphere during nucleation. Opposite to earlier studies with cluster mass spectrometers, we had no indication of neutral clusters. The reason is either less efficient charging of clusters in comparison to molecular sulphuric acid, or in low concentration of neutral clusters at our measurement site during these particular nucleation events. We show that utilizing high resolution mass spectrometry is crucial in separating the weak sulfuric acid cluster signal from the other compounds.

Citation: Jokinen, T., Sipilä, M., Junninen, H., Ehn, M., Lönn, G., Hakala, J., Petäjä, T., Mauldin III, R. L., Kulmala, M., and Worsnop, D. R.: Atmospheric sulphuric acid and neutral cluster measurements using CI-APi-TOF, Atmos. Chem. Phys. Discuss., 11, 31983-32002, doi:10.5194/acpd-11-31983-2011, 2011.
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