Atmos. Chem. Phys. Discuss., 11, 30773-30795, 2011
www.atmos-chem-phys-discuss.net/11/30773/2011/
doi:10.5194/acpd-11-30773-2011
© Author(s) 2011. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Seasonal variations of stable carbon isotopic ratios and biogenic tracer compounds of water-soluble organic aerosols in a deciduous forest
Y. Miyazaki1, P. Fu1, K. Kawamura1, Y. Mizoguchi2, and K. Yamanoi2
1Institute of Low Temperature Science, Hokkaido University, Sapporo, Japan
2Hokkaido Research Center, Forestry and Forest Products Research Institute, Sapporo, Japan

Abstract. To investigate the seasonal changes in biogenic water-soluble organic carbon (WSOC) aerosols in a boreal forest, aerosol samples were collected continuously in the canopy of a~deciduous forest in Northern Japan during 2009–2010. Stable carbon isotopic ratios of WSOC (δ13CWSOC) in aerosols exhibited a distinct seasonal cycle, with lower values from June through September (−25.5 ± 0.5‰). This cycle follows the net CO2 exchange between the forest ecosystem and the atmosphere, indicating that δ13CWSOC likely reflects the biological activity at the forest site. WSOC concentrations showed the highest values in early summer and autumn. Positive matrix factorization (PMF) analysis indicated that the factor in which biogenic secondary organic aerosols (BSOAs) dominated accounted for ~ 40% of the highest concentrations of WSOC, where BSOAs mostly consisted of α-/β-pinene SOA. In addition, primary biological aerosol particles (PBAPs) made similar contributions (~ 57%) to the WSOC near the canopy floor in early summer. This finding indicates that the production of both primary and secondary WSOC aerosols is important during the growing season in a deciduous forest. The methanesulfonic acid (MSA) maximum was also found in early summer and had a distinct vertical gradient with larger concentrations near the canopy floor. Together with the similar vertical gradients found for WSOC and δ13CWSOCas well as the α-/β-pinene SOA tracers, our results indicate that the forest floor, including ground vegetation and soil, acts as a significant source of the WSOC within a~forest canopy at the study site.

Citation: Miyazaki, Y., Fu, P., Kawamura, K., Mizoguchi, Y., and Yamanoi, K.: Seasonal variations of stable carbon isotopic ratios and biogenic tracer compounds of water-soluble organic aerosols in a deciduous forest, Atmos. Chem. Phys. Discuss., 11, 30773-30795, doi:10.5194/acpd-11-30773-2011, 2011.
 
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