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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-11-29601-2011</article-id>
<title-group>
<article-title>On the ice nucleation spectrum</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Barahona</surname>
<given-names>D.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Global Modeling and Assimilation Office, NASA Goddard Space Flight Center, Greenbelt, Maryland, USA</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>I.M. Systems Group Inc., Rockville, Maryland, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>02</day>
<month>11</month>
<year>2011</year>
</pub-date>
<volume>11</volume>
<issue>11</issue>
<fpage>29601</fpage>
<lpage>29646</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<abstract>
<p>This work presents a novel formulation of the ice nucleation spectrum, i.e.
the function relating the ice crystal concentration to cloud formation
conditions and aerosol properties. The new formulation relies on a
statistical view of the ice nucleation process and explicitly accounts for
the dependency of the ice crystal concentration on temperature,
supersaturation, cooling rate, and particle size, and, in the case of
heterogeneous ice nucleation, on the distributions of particle area and
surface composition. The new formulation is used to generate ice nucleation
parameterizations for the homogeneous freezing of cloud droplets and the
heterogeneous deposition ice nucleation on dust and soot ice nuclei. For
homogeneous freezing, it was found that by increasing the dispersion in the
droplet volume distribution the fraction of supercooled droplets in the
population increases. For heterogeneous ice nucleation it was found that ice
nucleation on efficient ice nuclei (IN) shows features consistent with the
singular hypothesis (characterized by a lack of temporal dependency of the
ice nucleation spectrum) whereas less efficient IN tend to display stochastic
behavior. Analysis of empirical nucleation spectra suggested that inferring
the aerosol heterogeneous ice nucleation properties from measurements of the
onset supersaturation and temperature may carry significant error as the
variability in ice nucleation properties within the aerosol population is not
accounted for. This work provides a simple and rigorous ice nucleation
framework were theoretical predictions, laboratory measurements and field
campaign data can be reconciled, and that is suitable for application in
atmospheric modeling studies.</p>
</abstract>
<counts><page-count count="46"/></counts>
</article-meta>
</front>
<body/>
<back>
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