Atmos. Chem. Phys. Discuss., 11, 29117-29139, 2011
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Atmospheric mercury observations from Antarctica: seasonal variation and source and sink region calculations
K. Aspmo Pfaffhuber1, T. Berg1,*, D. Hirdman1,**, and A. Stohl1
1Norwegian Institute for Air Research (NILU), Norway
*now at: Department of Chemistry, Norwegian University of Science and Technology, Norway
**now at: Centre for Environmental and Climate Research (CEC), Lund University, Sweden

Abstract. Long term atmospheric mercury measurements in the Southern Hemisphere are scarce and in Antarctica completely absent. Recent studies have shown that the Antarctic continent plays an important role in the global mercury cycle. Therefore, long term measurements of gaseous elemental mercury (GEM) were initiated at the Norwegian Antarctic Research Station, Troll (TRS) in order to improve our understanding of atmospheric transport, transformations and removal processes of GEM. GEM measurements started in February 2007 and are still ongoing, and this paper presents results from the first four years. The mean annual GEM concentration was 0.93±0.19 ng m−3 and is in good agreement with other recent southern hemispheric measurements. Measurements of GEM were combined with the output of the Lagrangian particle dispersion model FLEXPART, for a statistical analysis of GEM source and sink regions. It was found that the ocean is a source of GEM to TRS year round, especially in summer and fall. None of the Southern Hemisphere continents contribute significantly to the direct transport of GEM to TRS, but they are important for determining the overall GEM load in the Southern Hemisphere and for the mean GEM concentration at TRS. Further, the sea ice and marginal ice zones are GEM sinks in spring as also seen in the Arctic, but the Antarctic oceanic sink seems weaker. Contrary to the Arctic, a strong summer time GEM sink was found, when air originates from the Antarctic Plateau, which shows that the summertime removal mechanism of GEM is completely different and is caused by other chemical processes than the springtime atmospheric mercury depletion events. The results were corroborated by an analysis of ozone source and sink regions.

Citation: Aspmo Pfaffhuber, K., Berg, T., Hirdman, D., and Stohl, A.: Atmospheric mercury observations from Antarctica: seasonal variation and source and sink region calculations, Atmos. Chem. Phys. Discuss., 11, 29117-29139, doi:10.5194/acpd-11-29117-2011, 2011.
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