Atmos. Chem. Phys. Discuss., 11, 25327-25369, 2011
© Author(s) 2011. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Assessing filtering of mountaintop CO2 mixing ratios for application to inverse models of biosphere-atmosphere carbon exchange
B.-G. J. Brooks1, A. R. Desai1, B. B. Stephens2, D. R. Bowling3, S. P. Burns2, A. S. Watt2, S. L. Heck2,4, and C. Sweeney5
1Center for Climatic Research, University of Wisconsin-Madison, Madison, WI, USA
2National Center for Atmospheric Research, Boulder, CO, USA
3Department of Biology, University of Utah, Salt Lake City, UT, USA
4Department of Atmospheric and Oceanic Sciences, University of Colorado, Boulder, CO, USA
5Earth System Research Laboratory, NOAA, Boulder, CO, USA

Abstract. There is a widely recognized need to improve our understanding of biosphere-atmosphere carbon exchanges in areas of complex terrain including the United States Mountain West. CO2 fluxes over mountainous terrain are difficult to measure often due to unusual and complicated influences associated with atmospheric transport in complex terrain. Using five years of CO2 mixing ratio observations from the Regional Atmospheric Continuous CO2 Network in the Rocky Mountains (Rocky RACCOON), five statistical (subsetting) filters are used to investigate a range of approaches for identifying regionally representative CO2 mixing ratios. Test results from three filters indicate that subsets based on short-term variance and local CO2 gradients across tower inlet heights retain nine-tenths of the total observations and are able to define representative diurnal variability and seasonal cycles even for difficult-to-model sites where the influence of local fluxes is much larger than regional mixing ratio variations. Test results from two other filters that consider measurements from previous and following days using spline fitting or sliding windows are overly selective. Case study examples showed that even when standardized to common subset sizes these windowing-filters rejected measurements representing synoptic changes in CO2, which suggests that they are not well suited to filtering continental CO2 measurements. We present a novel CO2 lapse rate filter that uses CO2 differences between levels in the model atmosphere to constrain subsets of site measurements that are representative on model scales.

Citation: Brooks, B.-G. J., Desai, A. R., Stephens, B. B., Bowling, D. R., Burns, S. P., Watt, A. S., Heck, S. L., and Sweeney, C.: Assessing filtering of mountaintop CO2 mixing ratios for application to inverse models of biosphere-atmosphere carbon exchange, Atmos. Chem. Phys. Discuss., 11, 25327-25369, doi:10.5194/acpd-11-25327-2011, 2011.
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