Atmos. Chem. Phys. Discuss., 11, 21713-21767, 2011
www.atmos-chem-phys-discuss.net/11/21713/2011/
doi:10.5194/acpd-11-21713-2011
© Author(s) 2011. This work is distributed
under the Creative Commons Attribution 3.0 License.
Review Status
This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Typical types and formation mechanisms of haze in an eastern Asia megacity, Shanghai
K. Huang1,2, G. Zhuang1, Y. Lin1, J. S. Fu2, Q. Wang1, T. Liu1, R. Zhang1, Y. Jiang1, and C. Deng1
1Center for Atmospheric Chemistry Study, Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433, China
2Department of Civil and Environmental Engineering, The University of Tennessee, Knoxville, TN 37996, USA

Abstract. An intensive aerosol and gases campaign has been performed at Shanghai in the Yangtze River Delta region over Eastern China from late March to early June 2009. This study provided a complementary picture of typical haze types and formation mechanisms in megacities over China by using a synergy of ground-based monitoring, satellite observation and lidar inversion. During the whole study period, several extreme low visibility periods were observed with distinct characteristics, and three typical haze types were identified, i.e. secondary inorganic pollution, dust, and biomass burning. Sulfate, nitrate and ammonium accounted for a major part of PM2.5 mass during the secondary inorganic pollution, and the good correlation between SO2/NOx/CO and PM2.5 indicated that coal burning and vehicle emission were the major sources. Large-scale regions with high AOD and low Ångström exponent were detected by remote-sensing observation during the dust pollution episode, and this episode corresponded to coarse particles rich in mineral components such as Al and Ca with mineral aerosol contributing 76.8 % to TSP. The relatively low Ca/Al ratio of 0.75 combined with the air mass backward trajectory analysis suggested the dust source from Gobi Desert. Typical tracers for biomass burning from satellite observation (column CO and HCHO) and from ground measurement (CO, particulate K+, OC, and EC) were greatly enhanced during the biomass burning pollution episode. The exclusive linear correlation between CO and PM2.5 corroborated that organic aerosol dominated aerosol chemistry during biomass burning, and the high concentration and enrichment degree of arsenic (As) could be also partly derived from biomass burning. Aerosol optical profile observed by lidar demonstrated that aerosol was mainly constrained below the boundary layer and comprised of spheric aerosol (depolarization ratio <5 %) during the secondary inorganic and biomass burning episodes, while during the dust episode thick dust layer distributed at altitudes from near the ground to 1.4 km (average depolarization ratio = 0.122 ± 0.023) with dust accounting for 44–55 % of the total aerosol extinction coefficient. This study had illustrated a good picture of the typical haze types and proposed that identification of the complicated emission sources was important for the air quality improvement in megacities in China.

Citation: Huang, K., Zhuang, G., Lin, Y., Fu, J. S., Wang, Q., Liu, T., Zhang, R., Jiang, Y., and Deng, C.: Typical types and formation mechanisms of haze in an eastern Asia megacity, Shanghai, Atmos. Chem. Phys. Discuss., 11, 21713-21767, doi:10.5194/acpd-11-21713-2011, 2011.
 
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