Atmos. Chem. Phys. Discuss., 11, 18767-18821, 2011
www.atmos-chem-phys-discuss.net/11/18767/2011/
doi:10.5194/acpd-11-18767-2011
© Author(s) 2011. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
TransCom model simulations of CH4 and related species: linking transport, surface flux and chemical loss with CH4 variability in the troposphere and lower stratosphere
P. K. Patra1, S. Houweling2,3, M. Krol2,3,4, P. Bousquet5, D. Belikov6, D. Bergmann7, H. Bian8, P. Cameron-Smith7, M. P. Chipperfield9, K. Corbin10, A. Fortems-Cheiney5, A. Fraser11, E. Gloor9, P. Hess12, A. Ito1,6, S. R. Kawa8, R. M. Law10, Z. Loh10, S. Maksyutov6, L. Meng12, P. I. Palmer11, R. G. Prinn13, M. Rigby13, R. Saito1, and C. Wilson9
1Research Institute for Global Change/JAMSTEC, 3173-25 Show-machi, Yokohama, 2360001, Japan
2SRON Netherlands Institute for Space Research, Sorbonnelaan 2, 3584 CA Utrecht, The Netherlands
3Institute for Marine and Atmospheric Research Utrecht (IMAU), Princetonplein 5, 3584 CC Utrecht, The Netherlands
4Wageningen University and Research Centre, Droevendaalsesteeg 4, 6708 PB Wageningen, The Netherlands
5Universite de Versailles Saint Quentin en Yvelines (UVSQ), GIF sur YVETTE, France
6Center for Global Environmental Research, National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki, 305-8506, Japan
7Atmospheric, Earth, and Energy Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA
8Goddard Earth Sciences and Technology Center, NASA Goddard Space Flight Center, Code 613.3, Greenbelt, MD 20771, USA
9Institute for Climate and Atmospheric Science, School of Earth and Environment, niversity of Leeds, Leeds, LS2 9JT, UK
10Centre for Australian Weather and Climate Research, CSIRO Marine and Atmospheric Research, 107–121 Station St., Aspendale, VIC 3195, Australia
11School of Geosciences, University of Edinburgh, King's Buildings, West Mains Road, Edinburgh, EH9 3JN, UK
12Cornell University, 2140 Snee Hall, Ithaca, NY 14850, USA
13Center for Global Change Science, Building 54, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA

Abstract. A transport model intercomparison experiment (TransCom-CH4) has been designed to investigate the roles of surface emissions, transport and chemical loss in simulating the global methane distribution. Model simulations were conducted using twelve models and four model variants and results were archived for the period of 1990–2007. The transport and removal of six CH4 tracers with different emission scenarios were simulated, with net global emissions of 513 ± 9 and 514 ± 14 Tg CH4 yr−1 for the 1990s and 2000s, respectively. Additionally, sulfur hexafluoride (SF6) was simulated to check the interhemispheric transport, radon (222Rn) to check the subgrid scale transport, and methyl chloroform (CH3CCl3) to check the chemical removal by the tropospheric hydroxyl radical (OH). The results are compared to monthly or annual mean time series of CH4, SF6 and CH3CCl3 measurements from 8 selected background sites, and to satellite observations of CH4 in the upper troposphere and stratosphere. Most models adequately capture the vertical gradients in the stratosphere, the average long-term trends, seasonal cycles, interannual variations and interhemispheric gradients at the surface sites for SF6, CH3CCl3 and CH4. The vertical gradients of all tracers between the surface and the upper troposphere are consistent within the models, revealing vertical transport differences between models. We find that the interhemispheric exchange rate (1.39 ± 0.18 yr) derived from SF6 is faster by about 11 % in the 2000s compared to the 1990s. Up to 60 % of the interannual variations in the forward CH4 simulations can be explained by accounting for the interannual variations in emissions from biomass burning and wetlands. We also show that the decadal average growth rate likely reached equilibrium in the early 2000s due to the flattening of anthropogenic emission growth since the late 1990s. The modeled CH4 budget is shown to depend strongly on the troposphere-stratosphere exchange rate and thus to the model's vertical grid structure and circulation in the lower stratosphere. The 15-model median CH4 and CH3CCl3 atmospheric lifetimes are estimated to be 9.99 ± 0.08 and 4.61 ± 0.13 yr, respectively, with little interannual variability due to transport and temperature as noted by the ± 1 σ.

Citation: Patra, P. K., Houweling, S., Krol, M., Bousquet, P., Belikov, D., Bergmann, D., Bian, H., Cameron-Smith, P., Chipperfield, M. P., Corbin, K., Fortems-Cheiney, A., Fraser, A., Gloor, E., Hess, P., Ito, A., Kawa, S. R., Law, R. M., Loh, Z., Maksyutov, S., Meng, L., Palmer, P. I., Prinn, R. G., Rigby, M., Saito, R., and Wilson, C.: TransCom model simulations of CH4 and related species: linking transport, surface flux and chemical loss with CH4 variability in the troposphere and lower stratosphere, Atmos. Chem. Phys. Discuss., 11, 18767-18821, doi:10.5194/acpd-11-18767-2011, 2011.
 
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