Atmos. Chem. Phys. Discuss., 11, 10525-10555, 2011
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Wind speed dependent size-resolved parameterization for the organic enrichment of sea spray
B. Gantt1, N. Meskhidze1, M. C. Facchini2, M. Rinaldi2, D. Ceburnis3, and C. O'Dowd3
1North Carolina State University, Raleigh, NC, USA
2Institute of Atmospheric Sciences and Climate (ISAC), National Research Council (CNR), Bologna, Italy
3School of Physics and Centre for Climate and Air Pollution Studies, Ryan Institute, National University of Ireland Galway, University Road, Galway, Ireland

Abstract. For oceans to become a significant source of primary organic aerosol (POA), sea spray must be highly enriched with organics relative to the bulk seawater. We propose that organic enrichment at the air-sea interface, chemical composition of seawater, and the aerosol size are three main parameters controlling the organic mass fraction of sea spray aerosol (OMss). To test this hypothesis, we developed a new marine POA emission function based on a conceptual relationship between the organic enrichment at the air-sea interface and surface wind speed. The resulting parameterization is explored using aerosol chemical composition and surface wind speed from Atlantic and Pacific coastal stations, and satellite-derived ocean concentrations of chlorophyll-a, dissolved organic carbon, and particulate organic carbon. Of all the parameters examined, a multi-variable logistic regression revealed that the combination of 10 m wind speed and surface chlorophyll-a concentration ([Chl-a]) are the most consistent predictors of OMss. This relationship, combined the published aerosol size dependence of OMss, resulted in a new parameterization for the organic carbon fraction of sea spray. Global marine primary organic emission is investigated here by applying this newly-developed relationship to existing sea spray emission functions, satellite-derived [Chl-a], and modeled 10 meter winds. Analysis of model simulations show that global annual submicron marine organic emission associated with sea spray is estimated to be from 2.8 to 5.6 Tg C yr−1. This study provides additional evidence that marine primary organic aerosols are a globally significant source of organics in the atmosphere.

Citation: Gantt, B., Meskhidze, N., Facchini, M. C., Rinaldi, M., Ceburnis, D., and O'Dowd, C.: Wind speed dependent size-resolved parameterization for the organic enrichment of sea spray, Atmos. Chem. Phys. Discuss., 11, 10525-10555, doi:10.5194/acpd-11-10525-2011, 2011.
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