1The Cyprus Institute, Energy, Environment and Water Research Center, P.O. Box 27456, 1645 Nicosia, Cyprus
2Air Chemistry Department, Max-Planck Institute of Chemistry, P.O. Box 3060, 55020 Mainz, Germany
3DLR, Institut fuer Physik der Atmosphaere, Oberpfaffenhofen, 82234 Wessling, Germany
4Institute of Arctic and Alpine Research (INSTAAR), University of Colorado, UCB 450, CO 80309, USA
5NOAA/ESRL, 325 Broadway, Boulder, CO 80303, USA
Abstract. The primary sources and atmospheric chemistry of C2−C5 alkanes have been incorporated into the atmospheric chemistry general circulation model EMAC. Model output is compared with new observations from the NOAA/ESRL GMD cooperative air sampling network. Based on the global coverage of the data, two different anthropogenic emission datasets for C4−C5 alkanes, widely used in the modelling community, are evaluated. We show that the model reproduces the main atmospheric features of the C2−C5 alkanes (e.g., seasonality). While the simulated values of ethane and propane are within a 20% range of the measurements, larger deviations are found for the other tracers. Finally the effect of C3−C5 alkanes on the concentration of acetone and acetaldehyde are assessed. Their chemical sources are largely controlled by the reaction with OH, while the reactions with NO3 and Cl contribute only to a little extent. The total amount of acetone produced by propane, i-butane and i-pentane oxidation is 11.2 Tg/yr, 4.2 Tg/yr and 5.8 Tg/yr, respectively. Moreover, 3.1, 3.3, 1.4 and 4.8 Tg/yr of acetaldehyde are formed by the oxidation of propane, n-butane, n-pentane and i-pentane, respectively.