Atmos. Chem. Phys. Discuss., 10, 5233-5564, 2010
www.atmos-chem-phys-discuss.net/10/5233/2010/
doi:10.5194/acpd-10-5233-2010
© Author(s) 2010. This work is distributed
under the Creative Commons Attribution 3.0 License.
Review Status
This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V – heterogeneous reactions on solid substrates
J. N. Crowley1, M. Ammann2, R. A. Cox3, R. G. Hynes4, M. E. Jenkin5, A. Mellouki6, M. J. Rossi7, J. Troe8, and T. J. Wallington9,*
1Max-Planck-Institut für Chemie, Division of Atmospheric Chemistry, Postfach 3060, 55020 Mainz, Germany
2Laboratory of Radiochemistry and Environmental Chemistry, Paul Scherrer Institute 5232 Villigen, Switzerland
3Centre for Atmospheric Science, Dept. of Chemistry, University of Cambridge, Lensfield Road Cambridge CB2 1EP, UK
4CSIRO Energy Technology, Lucas Heights Science and Technology Centre, Building 2, PMB7, Bangor, NSW 2234, Australia
5Atmospheric Chemistry Services, Whistley Down,Yelverton, Devon PL20 6EN, UK
6ICARE (Institut de Combustion, Arothermique, Réactivité et Environnement) CNRS (Centre National de la Recherche Scientifique) – UPR3021, 1C, Avenue de la recherche scientifique, 45071 Orleans cedex 02, France
7Laboratorium fuer Atmosphaerenchemie (LAC), OFLA008 Paul Scherrer Institut (PSI), 5232 Villigen PSI, Switzerland
8Institute of Physical Chemistry, University of Goettingen, Tammannstr. 6, 7077 Göttingen, Germany
9Ford Motor Company, Research and Advanced Engineering, Mail Drop RIC-2122, Dearborn, Michigan 48121-2053, USA
*The IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry

Abstract. This article, the fifth in the ACP journal series, presents data evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the heterogeneous processes on surfaces of solid particles present in the atmosphere, for which uptake coefficients and adsorption parameters have been presented on the IUPAC website in 2009. The article consists of an introduction and guide to the evaluation, giving a unifying framework for parameterisation of atmospheric heterogeneous processes. We provide summary sheets containing the recommended uptake parameters for the evaluated processes. Four substantial appendices contain detailed data sheets for each process considered for ice, mineral dust, sulfuric acid hydrate and nitric acid hydrate surfaces, which provide information upon which the recommendations are made.

Citation: Crowley, J. N., Ammann, M., Cox, R. A., Hynes, R. G., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V – heterogeneous reactions on solid substrates, Atmos. Chem. Phys. Discuss., 10, 5233-5564, doi:10.5194/acpd-10-5233-2010, 2010.
 
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