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<article language="en">
	<journal>
		<journal_title>Atmospheric Chemistry and Physics Discussions</journal_title>
		<journal_url>www.atmos-chem-phys-discuss.net</journal_url>
		<issn>1680-7367</issn>
		<eissn>1680-7375</eissn>
		<volume_number>10</volume_number>
		<issue_number>2</issue_number>
		<publication_year>2010</publication_year>
	</journal>
	<doi>10.5194/acpd-10-3807-2010</doi>
	<article_url>http://www.atmos-chem-phys-discuss.net/10/3807/2010/</article_url>
	<abstract_html>http://www.atmos-chem-phys-discuss.net/10/3807/2010/acpd-10-3807-2010.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys-discuss.net/10/3807/2010/acpd-10-3807-2010.pdf</fulltext_pdf>
	<start_page>3807</start_page>
	<end_page>3826</end_page>
	<publication_date>2010-02-10</publication_date>
	<article_title content_type="html">Are there urban signatures in the tropospheric ozone column products derived from satellite measurements?</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>J. Kar</name>
			<email>jayanta.kar@nasa.gov</email>
		</author>
		<author numeration="2" affiliations="2">
			<name>J. Fishman</name>
		</author>
		<author numeration="3" affiliations="1,2">
			<name>J. K. Creilson</name>
		</author>
		<author numeration="4" affiliations="3">
			<name>A. Richter</name>
		</author>
		<author numeration="5" affiliations="4">
			<name>J. Ziemke</name>
		</author>
		<author numeration="6" affiliations="4">
			<name>S. Chandra</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Science Systems and Applications Inc., Hampton, VA, 23666, USA</affiliation>
		<affiliation numeration="2" content_type="html">NASA Langley Research Center, Hampton, VA, 23681, USA</affiliation>
		<affiliation numeration="3" content_type="html">Institute of Environmental Physics, University of Bremen, Bremen, Germany</affiliation>
		<affiliation numeration="4" content_type="html">GEST, University of Maryland, Baltimore, MD, USA</affiliation>
	</affiliations>
	<abstract content_type="html">In view of the proposed geostationary satellite missions to monitor
      air quality from space, it is important to first assess the capability
      of the current suite of satellite instruments to provide information
      on the urban scale pollution. We explore the possibility of detecting
      urban signatures in the tropospheric column ozone data derived from
      TOMS/SBUV and OMI/MLS satellite data. We find that distinct isolated
      plumes of tropospheric ozone near several large and polluted cities
      around the world may be detected in these data sets. The ozone plumes
      generally correspond with the tropospheric column NO&lt;sub&gt;2&lt;/sub&gt; plumes
      around these cities as observed by the SCIAMACHY instrument. Similar
      plumes are also seen in tropospheric mean ozone mixing ratio
      distribution after accounting for the surface and tropopause pressure
      variations. The total column ozone retrievals indicate fairly
      significant sensitivity to the lower troposphere over the polluted
      land areas, which might help explain these detections. These results
      indicate that UV measurements may, in principle, be able to capture
      the urban signatures and may have implications for future missions
      using geostationary satellites.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Beirle,~S., Platt,~U., Wenig,~M., and Wagner,~T.: Weekly cycle of \chemNO_2 by GOME measurements: a~signature of anthropogenic sources, Atmos. Chem. Phys., 3, 2225–2232, 2003. </reference>
		<reference numeration="2" content_type="text"> Boersma,~K F., Jacob,~D J., Trainic,~M., Rudich,~Y., DeSmedt,~I., Dirksen,~R., and Eskes,~H J.: Validation of urban NO&lt;sub&gt;2&lt;/sub&gt; concentrations and their diurnal and seasonal variations observed from the SCIAMACHY and OMI sensors using in situ surface measurements in Israeli cities, Atmos. Chem. Phys., 9, 3867–3879, 2009. </reference>
		<reference numeration="3" content_type="text"> Chatfield,~R., Schoeberl,~M., Stajner,~I., Wargan,~K., Oltmans,~S., and Thompson,~A.: Evaluation of lower tropospheric ozone estimates based on OMI and MLS for pollution studies and a~California example, Eos T. Am. Geophys. Un., 89(23), Jt. Assem. Suppl., Abstract A23A-04, 2008a. </reference>
		<reference numeration="4" content_type="text"> Chatfield,~R., Bhartia,~P K., Schoeberl,~M., Liu,~X., Oltmans,~S., Esswein,~R., Tarasick,~D., and Thompson,~A M.: How well do OMI&apos;s UV-based retrievals sample the lowermost troposphere, AURA Science Team Meeting, Baltimore, 27–30 October 2008b. </reference>
		<reference numeration="5" content_type="text"> Clerbaux,~C., Edwards,~D P., Deeter,~M., Emmons,~L., Lamarque,~J.-F., Tie,~X X., Massie,~S T., and Gille,~J C.: Carbon monoxide pollution from cities and urban areas observed by the Terra/MOPITT mission, Geophys. Res. Lett., 35, L03817, \doi10.1029/2007GL032300, 2008. </reference>
		<reference numeration="6" content_type="text"> Diab,~R D., Raghunandan,~A., Thompson,~A M., and Thouret,~V.: Classification of tropospheric ozone profiles over Johannesburg based on mozaic aircraft data, Atmos. Chem. Phys., 3, 713–723, 2003. </reference>
		<reference numeration="7" content_type="text"> Duncan,~B N., West,~J J., Yoshida,~Y., Fiore,~A M., and Ziemke,~J R.: The influence of European pollution on ozone in the Near East and northern Africa, Atmos. Chem. Phys., 8, 2267–2283, 2008. </reference>
		<reference numeration="8" content_type="text"> Eremenko,~M., Dufour,~G., Foret,~G., Keim,~C., Orphal,~J., Beekmann,~M., Bergametti,~G., and Flaud,~J.-M.: Tropospheric ozone distributions over Europe during the heat wave in July 2007 observed from infrared nadir spectra recorded by IASI, Geophys. Res. Lett., 35, L18805, \doi10.1029/2008GL034803, 2008. </reference>
		<reference numeration="9" content_type="text"> Fishman,~J. and Balok,~A E.: Calculation of daily tropospheric ozone residuals using TOMS and empirically improved SBUV measurements: application to an ozone pollution episode over the Eastern United States, J Geophys. Res., 104, 30319–30340, 1999. </reference>
		<reference numeration="10" content_type="text"> Fishman,~J., Watson,~C E., Larsen,~J C., and Logan,~J A.: Distribution of tropospheric ozone determined from satellite data, J. Geophys. Res., 95, 3599–3617, 1990. </reference>
		<reference numeration="11" content_type="text"> Fishman,~J., Brackett,~V G., Browell,~E V., and Grant,~W B.: Tropospheric ozone derived from TOMS/SBUV measurements during TRACE-A, J Geophys. Res., 101(D19), 24069–24082, 1996. </reference>
		<reference numeration="12" content_type="text"> Fishman,~J., Wozniak,~A E., and Creilson,~J K.: Global distribution of tropospheric ozone from satellite measurements using the empirically corrected tropospheric ozone residual technique: Identification of the regional aspects of air pollution, Atmos. Chem. Phys., 3, 893–907, 2003. </reference>
		<reference numeration="13" content_type="text"> Fishman,~J., Creilson,~J K., Wozniak,~A E., and Crutzen,~P J.: Interannual variability of stratospheric and tropospheric ozone determined from satellite measurements, J Geophys. Res., 110, D20306, \doi10.1029/2005JD005868, 2005. </reference>
		<reference numeration="14" content_type="text"> Fishman,~J., Bowman,~K W., Burrows,~J P., Richter,~A., Chance,~K V., Edwards,~D P., Martin,~R V., Morris,~G A., Pierce,~R B., Ziemke,~J R., Al-Saadi,~J A., Creilson,~J K., Schaack,~T K., and Thompson,~A M.: Remote sensing of tropospheric pollution from space, B Am. Meteorol. Soc., 89, 805–821, 2008. </reference>
		<reference numeration="15" content_type="text"> Fishman,~J., Creilson,~J K., Parker,~P A., Ainsworth,~E A., Vining,~G G., and Szarka J L.: A~new satellite measurement capability for assessing damage to crops from regional scale ozone pollution, Eos T. Am. Geophys. Un., 90(22), Jt. Assem. Suppl., Abstract A72B-05, 2009. </reference>
		<reference numeration="16" content_type="text"> Gonçalves,~M., Jiménez-Guerrero,~P., and Baldasano,~J M.: Contribution of atmospheric processes affecting the dynamics of air pollution in South-Western Europe during a~typical summertime photochemical episode, Atmos. Chem. Phys., 9, 849–864, 2009. </reference>
		<reference numeration="17" content_type="text"> Gurjar,~B R., Butler,~T M., Lawrence,~M G., and Lelieveld,~J.: Evaluation of emissions and air quality in megacities, Atmos. Environ., 42, 1593–1606, 2008. </reference>
		<reference numeration="18" content_type="text"> Henne,~S., Furger,~M., Nyeki,~S., Steinbacher,~M., Neininger,~B., de Wekker,~S F J., Dommen,~J., Spichtinger,~N., Stohl,~A., and Prévôt,~A S H.: Quantification of topographic venting of boundary layer air to the free troposphere, Atmos. Chem. Phys., 4, 497–509, 2004. </reference>
		<reference numeration="19" content_type="text"> Kar,~J., Drummond,~J R., Jones,~D B A., Liu,~J., Nichitiu,~F., Zou,~J., Gille.,~J C., Edwards,~D P., and Deeter,~M N.: Carbon monoxide (CO) maximum over the Zagros mountains in the Middle East: signature of mountain venting?, Geophys. Res. Lett., 33, L15819, \doi10.1029/2006GL026231, 2006. </reference>
		<reference numeration="20" content_type="text"> Kar,~J., Jones,~D B A., Drummond,~J R., Attie,~J L., Liu,~J., Zou,~J., Nichitiu,~F., Seymour,~M D., Edwards,~D P., Deeter,~M N., Gille,~J C., and Richter,~A.: Measurement of low altitude CO over the Indian subcontinent by MOPITT, J Geophys. Res., 113, D16307, \doi10.1029/2007JD009362, 2008. </reference>
		<reference numeration="21" content_type="text"> Liu,~X., Chance,~K., Sioris,~C E., Spurr,~R J D., Kurosu,~T P., Martin,~R V., and Newchurch,~M J.: Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment: algorithm description and validation, J Geophys. Res., 110, D20307, \doi10.1029/2005JD006240, 2005. </reference>
		<reference numeration="22" content_type="text"> Liu, X., Bhartia, P. K., Chance, K., Spurr, R. J. D., and Kurosu, T. P.: Ozone profile retrievals from the Ozone Monitoring Instrument, Atmos. Chem. Phys. Discuss., 9, 22693–22738, 2009 </reference>
		<reference numeration="23" content_type="text"> Martin,~R V.: Satellite remote sensing of surface air quality, Atmos. Environ., 42, 7823–7843, 2008. </reference>
		<reference numeration="24" content_type="text"> Mena-Carrasco,~M., Carmichael,~G R., Campbell,~J E., Zimmerman,~D., Tang,~Y., Adhikary,~B., D&apos;allura,~A., Molina,~L T., Zavala,~M., Garc\&apos;ia,~A., Flocke,~F., Campos,~T., Weinheimer,~A J., Shetter,~R., Apel,~E., Montzka,~D D., Knapp,~D J., and Zheng,~W.: Assessing the regional impacts of Mexico City emissions on air quality and chemistry, Atmos. Chem. Phys., 9, 3731–3743, 2009. </reference>
		<reference numeration="25" content_type="text"> Molina,~L T., Kolb,~C E., de Foy,~B., Lamb,~B K., Brune,~W H., Jimenez,~J L., Ramos-Villegas,~R., Sarmiento,~J., Paramo-Figueroa,~V H., Cardenas,~B., Gutierrez-Avedoy,~V., and Molina,~M J.: Air quality in North America&apos;s most populous city – overview of the MCMA-2003 campaign, Atmos. Chem. Phys., 7, 2447–2473, 2007. </reference>
		<reference numeration="26" content_type="text"> Richter,~A., Burrows,~J P., Nub,~H., Granier,~C., and Niemeier,~U.: Increase in tropospheric nitrogen dioxide over China observed from space, Nature, 437, 129–132, \doi10.1038/\breaknature04092, 2005. </reference>
		<reference numeration="27" content_type="text"> Sillman,~S., Samson,~P J., and Masters,~J M.: Ozone production in urban plumes transported over water: photochemical model and case studies in the Northeastern and Midwestern United States, J Geophys. Res., 98(D7), 12687–12699, 1993. </reference>
		<reference numeration="28" content_type="text"> Shim,~C., Li,~Q., Luo,~M., Kulawik,~S., Worden,~H., Worden,~J. , Eldering,~A., Diskin,~G., Sachse,~G., Weinheimer,~A., Knapp,~D., Montzca,~D. and Campos,~T.: Satellite observations of Mexico City pollution outflow from the Tropospheric Emissions Spectrometer (TES), Atmos. Environ., 43, 1540–1547, 2009. </reference>
		<reference numeration="29" content_type="text"> Spicer,~C W., Joseph,~D W., Sticksel,~P R., and Ward,~G F.: Ozone sources and transport in the North Eastern United States, Environ. Sci. Technol., 13, 975–985, 1979. </reference>
		<reference numeration="30" content_type="text"> Tie,~X., Madronich,~S., Li,~G., Ying,~Z., Weinheimer,~A., Apel,~E., and Campos,~T.: Simulation of Mexico City plumes during the MIRAGE-Mex field campaign using the WRF-Chem model, Atmos. Chem. Phys., 9, 4621–4638, 2009. </reference>
		<reference numeration="31" content_type="text"> Ziemke,~J R., Chandra,~S., and Bhartiya,~P K.: \qutCloud slicing: a~new technique to derive upper tropospheric ozone from satellite measurements, J Geophys. Res., 106, 9853–9867, 2001. </reference>
		<reference numeration="32" content_type="text"> Ziemke,~J R., Chandra,~S., Duncan,~B N., Froidevaux,~L., Bhartia,~P K., Levelt,~P F., and Waters,~J W.: Tropospheric ozone determined from Aura OMI and MLS: evaluation of measurements and comparison with the Global Modeling Initiative&apos;s Chemical Transport Model, J Geophys. Res., 111, D19303, \doi10.1029/2006JD007089, 2006. </reference>
	</references>
</article>

