Atmos. Chem. Phys. Discuss., 10, 21989-22018, 2010
www.atmos-chem-phys-discuss.net/10/21989/2010/
doi:10.5194/acpd-10-21989-2010
© Author(s) 2010. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Modelling of base cation emissions, concentrations and deposition in the UK
M. Werner1, M. Kryza1, A. J. Dore2, M. Błaś1, S. Hallsworth2, M. Vieno2,3, S. Tang3, and R. Smith3
1Department of Climatology and Atmosphere Protection, University of Wrocław, Poland
2Centre for Ecology and Hydrology, Edinburgh, UK
3School of GeoScience, University of Edinburgh, UK

Abstract. Base cations exerts a large impact on various geochemical and geophysical processes both in the atmosphere and at the Earth surface. One of the essential roles of these compounds is impact on surface pH causing an increase in alkalinity and neutralizing the effects of acidity generated by sulphur and nitrogen deposition. During recent years anthropogenic emissions of base cations in the UK have decreased substantially, by about 70% for Na+, 78% for Mg2+, 75% for Ca2+ and about 48% for K+ for the period 1990–2006. For the island regions, such as the is UK, the main source of base cation particles is the aerosol produced from the sea surface. Here, the sea salt aerosol (SSA) emissions are calculated with parameterisations proposed by Maårtensson et al. (2003); ultra fine particles, Monahan et al. (1986); fine particles and Smith and Harisson (1998); coarse particles continuously with a 0.1 μ m size step using WRF-modelled wind speed data at a 5 km × 5 km grid square resolution with a 3 h time step for two selected years 2003 and 2006. SSA production has been converted into base cation emissions, with the assumption that the chemical composition of the particle emitted from the sea surface is equal to the chemical composition of sea water, and used as input data in the Fine Resolution Atmospheric Multi-pollutant Exchange Model (FRAME). FRAME model results, yearly mean concentrations and total wet deposition at a 5 km × 5 km grid resolution, are compared with concentrations in air and wet deposition from the National Monitoring Network and measurements based estimates of UK deposition budget. The correlation coefficient for wet deposition achieves high values for Na+ and Mg2+, and for Ca2+ there is significant scattering. Base cation concentration is also represented well, with some overestimations on the west coast and underestimations in the centre of the land.

Citation: Werner, M., Kryza, M., Dore, A. J., Błaś, M., Hallsworth, S., Vieno, M., Tang, S., and Smith, R.: Modelling of base cation emissions, concentrations and deposition in the UK, Atmos. Chem. Phys. Discuss., 10, 21989-22018, doi:10.5194/acpd-10-21989-2010, 2010.
 
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