Atmos. Chem. Phys. Discuss., 10, 153-182, 2010
www.atmos-chem-phys-discuss.net/10/153/2010/
doi:10.5194/acpd-10-153-2010
© Author(s) 2010. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Fast two-dimensional GC-MS with thermal extraction for anhydro-sugars in fine aerosols
Y. Ma1,*, M. D. Hays1, C. D. Geron1, J. T. Walker1, and M. J. Gatari Gichuru2
1National Risk Management Research Laboratory, United States Environmental Protection Agency, Research Triangle Park, North Carolina 27711, USA
2Institute of Nuclear Science & Technology, College of Architecture and Engineering, University of Nairobi, Nairobi, Kenya
*now at: California Air Resources Board, 9528 Telstar Avenue, El Monte, CA 91731, USA

Abstract. A fast two-dimensional gas chromatography (GC-MS) method that uses heart-cutting and thermal extraction (TE) and requires no chemical derivatization was developed for the determination of anhydro-sugars in fine aerosols. Evaluation of the TE-GC-GC-MS method shows high average relative accuracy (≥90%), reproducibility (≤10% relative standard deviation), detection limits of less than 3 ng/μL, and negligible carryover for levoglucosan, mannosan, and galactosan markers. TE-GC-GC-MS- and solvent extraction (SE)-GC-MS-measured levoglucosan concentrations correlate across several diverse types of biomass burning aerosols. Because the SE-GC-MS measurements were taken 8 years prior to the TE-GC-GC-MS ones, the stability of levoglucosan is established for quartz filter-collected biomass burning aerosol samples stored at ultra-low temperature (–45°C). Levoglucosan concentrations (w/w) in aerosols collected following atmospheric dilution near open fires of varying intensity are similar to those in biomass burning aerosols produced in a laboratory enclosure. An average levoglucosan-mannosan-galactosan ratio of 15:2:1 is observed for these two aerosol sets. TE-GC-GC-MS analysis of atmospheric aerosols from the US and Africa produced levoglucosan concentrations (0.01–1.6 μg/m3) well within those reported for aerosols collected globally and examined using different analytical techniques (0.004–7.6 μg/m3). Further comparisons among techniques suggest that fast TE-GC-GC-MS is among the most sensitive, accurate, and precise methods for compound-specific quantification of anhydro-sugars. In addition, an approximately twofold increase in aerosol sample throughput may be realized when combining TE with fast chromatography for anhydro-sugar determination.

Citation: Ma, Y., Hays, M. D., Geron, C. D., Walker, J. T., and Gatari Gichuru, M. J.: Fast two-dimensional GC-MS with thermal extraction for anhydro-sugars in fine aerosols, Atmos. Chem. Phys. Discuss., 10, 153-182, doi:10.5194/acpd-10-153-2010, 2010.
 
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